Abstract
anti-[2.2](1,4)Triphenylenophane was synthesized by the Pd-catalyzed double cross-coupling of 4,5,12,13-tetrabromo[2.2]paracyclophane with 9,9-dimethyl-9-stannafluorene. There have been no reports on the synthesis of simple triphenylene-stacked molecules in the 75-year history of cyclophane. Its structure and properties were experimentally and theoretically studied.
Triphenylenophane was synthesized by the Pd-catalyzed double cross-coupling of 4,5,12,13-tetrabromo[2.2]paracyclophane with 9,9-dimethyl-9-stannafluorene. There have been no reports on the synthesis of simple triphenylene-stacked molecules in the 75-year history of cyclophane. Its structure and properties were experimentally and theoretically studied.](https://oup.silverchair-cdn.com/oup/backfile/Content_public/Journal/chemlett/53/1/10.1093_chemle_upad018/2/m_upad018_ga1.jpeg?Expires=1750312934&Signature=DvcW1JSEYCE9DFaq~sYIB9DFF83qlSdNIPBcU8rTSfCsgdhzTy~y9c5oUowrHp0Kg8ABoyxDuhcTINIC5X7uQHD-FSJS2gItuwS3VKyyFmgpJnD8kPhR4OlygP2SOAtBJJlPSae7fWkVNNpSGYbR670hSPQZWKkRdWZCWdOKetbtG5ekCAg2WOkR5Dck4GGvml1RdCu2qDp0c8sdWBhR~0WwJVfoM2a5ctnAV11wUldV3crZ6kO7p7iKRZbn1EqfoCKcwSAYa-jWRyzSOvqGLQ7EPtnwgAfPsJw-8rYj9TulJ~0ZUZGQxgiDkbW1nFipRT3x1KxvpDzNtRSJii7zUA__&Key-Pair-Id=APKAIE5G5CRDK6RD3PGA)
anti-[2.2](1,4)Triphenylenophane was synthesized by the Pd-catalyzed double cross-coupling of 4,5,12,13-tetrabromo[2.2]paracyclophane with 9,9-dimethyl-9-stannafluorene. There have been no reports on the synthesis of simple triphenylene-stacked molecules in the 75-year history of cyclophane. Its structure and properties were experimentally and theoretically studied.
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