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Kiyoshi Ezumi, Hiroshi Nakai, Shigeru Sakata, Koichi Nishikida, Motoo Shiro, Tanekazu Kubota, THE IMPORTANCE OF INTRAMOLECULAR CHARGE TRANSFER EFFECT ON THE MOLECULAR CONFIGURATION OF p-NITROBENZYLIDENE-p-DIMETHYLAMINOANILINE, Chemistry Letters, Volume 3, Issue 11, November 1974, Pages 1393–1398, https://doi.org/10.1246/cl.1974.1393
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Abstract
The structure of p-nitrobenzylidene-p-dimethylaminoaniline [I] was determined as planar transconfiguration. This is quite different from the structure of benzylideneaniline etc., which are not planar. It is stressed that the intramolecular charge transfer interaction between the substituents in [I] may play an important role for the configuration.
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© 1974 The Chemical Society of Japan
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