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Yoshiki Chujo, Kazuo Tanaka, New Polymeric Materials Based on Element-Blocks, Bulletin of the Chemical Society of Japan, Volume 88, Issue 5, May 2015, Pages 633–643, https://doi.org/10.1246/bcsj.20150081
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Abstract
The concept and representative examples of “element-block polymers” are described. A structural unit consisting of various groups of elements is called an “element-block.” In this review, unique properties of “element-block polymers” composed of organoboron complexes, o-carboranes, and polyhedral oligomeric silsesquioxanes as typical examples of element blocks are illustrated. The design and synthesis of new element-blocks and development of methods forming higher-order structures for realizing the desired functions based on a bottom-up approach are explained.
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