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Yuichi Shimakawa, Reduction and Oxidation of Transition-Metal Oxide Thin Films: Solid-State Chemistry with Epitaxially Grown Thin Films, Bulletin of the Chemical Society of Japan, Volume 86, Issue 3, March 2013, Pages 299–311, https://doi.org/10.1246/bcsj.20120277
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Abstract
Reduction and oxidation of perovskite-structure transition-metal oxide thin films are highlighted. Oxygen ions are released from and incorporated into the perovskite-structure framework during the reduction and oxidation. Low-temperature topochemical reduction reaction with CaH2 enables us to prepare infinite-layer structure oxide thin films containing Fe and Ni. With the epitaxially grown thin film samples, anisotropic rearrangement and transfer of oxygen ions in the structures have been revealed. Selective reduction of layers in artificial superlattices was also found, and the observed behavior suggests that the oxygen-ion mobility in the artificial superlattices was confined within the two-dimensional brownmillerite layer. Specific structural features play important roles in the oxygen-ion transfer in solids at low temperatures. The obtained results would be a key to develop technologies related to energy and the environment.
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