Abstract

The charge-transfer complex of 2,7-bis(methylthio)-1,6-dithiapyrene (MTDTPY) with tetracyano-2,6-naphthoquinodimethane (TNAP) showed an alternated stacking mode of crystal structure. There are no short intermolecular contacts. The ionicity was estimated to be neutral based on an analysis of the IR stretching frequency of the CN groups and the transition energy of the charge-transfer band.

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