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Jiro Toyoda, Akio Oda, Ichiro Murata, Atsushi Kawamoto, Jiro Tanaka, Kazuhiro Nakasuji, Crystal Structure of an Alternated Stacking Charge-Transfer Complex of 2,7-Bis(methylthio)-1,6-dithiapyrene (MTDTPY) with Tetracyano-2,6-naphthoquinodimethane (TNAP), Bulletin of the Chemical Society of Japan, Volume 66, Issue 7, July 1993, Pages 2115–2117, https://doi.org/10.1246/bcsj.66.2115
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Abstract
The charge-transfer complex of 2,7-bis(methylthio)-1,6-dithiapyrene (MTDTPY) with tetracyano-2,6-naphthoquinodimethane (TNAP) showed an alternated stacking mode of crystal structure. There are no short intermolecular contacts. The ionicity was estimated to be neutral based on an analysis of the IR stretching frequency of the CN groups and the transition energy of the charge-transfer band.