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Akiko Furuhashi, Kunihiko Endo, Shiro Takagi, Yukichi Yoshino, Synthesis and Reaction of trans-Dichlorobis(o-phenylenediamine)rhodium(III) Perchlorate with Some Oxidizing Agents, Bulletin of the Chemical Society of Japan, Volume 64, Issue 1, January 1991, Pages 298–300, https://doi.org/10.1246/bcsj.64.298
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Abstract
A new rhodium(III) complex with o-phenylenediamine, trans-[RhCl2{C6H4(NH2)2}2]ClO4 was synthesized and the reaction with oxidizing agents studied. Due to coordination with the rhodium(III) ion the o-phenylenediamine (opd) was greatly stabilized against oxidation and the complex was oxidized slowly by periodate via intermediate radical complex to bis(o-benzoquinone diimine)dichlororhodium(III) complex which decomposed to the final products.