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Yuan Kou, Nobuo Yamada, Susumu Akutagawa, Geng Zhang, Kozo Tanabe, Acidic Property of Rh and Ru Complexes, Bulletin of the Chemical Society of Japan, Volume 64, Issue 1, January 1991, Pages 133–135, https://doi.org/10.1246/bcsj.64.133
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Abstract
The acidic property of [Rh(nbd)(dppb)]ClO4, [Ru(binap)](BF4)2, and [Ru(dmso)6](ClO4)2 was measured by using the acetalization of cyclohexanone as a test reaction and the temperature-programmed desorption [TPD] of pyridine. The acid strengths were estimated to be H0=−2.1 for [Ru(dmso)6](ClO4)2 and H0=−2.2 for [Ru(binap)](BF4)2 and [Rh(nbd)(dppb)]ClO4 by the test reaction method. The TPD method gave consistent results.
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© 1991 The Chemical Society of Japan
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