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Fumiyuki Ozawa, Kunihiko Kurihara, Takakazu Yamamoto, Akio Yamamoto, Alteration of Reaction Course in Thermolysis of cis-Diethylbis(tertiary phosphine)palladium(II) from Reductive Elimination to β-Elimination Process Induced by Addition of Tertiary Phosphine Ligand, Bulletin of the Chemical Society of Japan, Volume 58, Issue 1, January 1985, Pages 399–400, https://doi.org/10.1246/bcsj.58.399
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Abstract
Addition of tertiary phosphine to a solution containing cis-diethylbis(tertiary phosphine)palladium(II) alters thermolysis course of the complex from reductive elimination process liberating butane to β-hydrogen elimination process in which ethane and ethylene are released. Study with a deuterium-labeled ethyl complex indicates involvement of an internal metalation process.