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Shunta Koga, Yusuke Tsukamoto, Satoshi Okuzumi, Masahiro N Machida, Dependence of Hall coefficient on grain size and cosmic ray rate and implication for circumstellar disc formation, Monthly Notices of the Royal Astronomical Society, Volume 484, Issue 2, April 2019, Pages 2119–2136, https://doi.org/10.1093/mnras/sty3524
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ABSTRACT
The Hall effect plays a significant role in star formation, because it induces rotation in the infalling envelope, which in turn affects the formation and evolution of the circumstellar disc. The importance of the Hall effect varies with the Hall coefficient, and this coefficient is determined by the fractional abundances of charged species. These abundance values are primarily based on the size and quantity of dust grains as well as the cosmic ray intensity, which, respectively, absorb and create charged species. Thus, the Hall coefficient varies with both the properties of dust grains and the cosmic ray rate (or ionization source). In this study, we explore the dependence of the Hall coefficient on the grain size and cosmic ray ionization rate using a simplified chemical network model. Following this, using an analytic model, we estimate the typical size of a circumstellar disc induced solely by the Hall effect. The results show that the disc grows during the main accretion phase to a size of ∼3–100 au, with the actual size depending on the parameters. These findings suggest that the Hall effect greatly affects circumstellar disc formation, especially in the case that the dust grains have a typical size of |${\sim } 0.025 - 0.075\, \mu {\rm m}$|.
1 INTRODUCTION
It is important to elucidate the process by which stars are formed, because stars are the fundamental constituents of the Universe and because star formation is associated with the origin of planets. Observations indicate that the magnetic energy in prestellar clouds is comparable to the gravitational energy (Crutcher et al. 2010). This large quantity of magnetic energy (that is, a strong Lorentz force) affects the star formation process. For example, magnetic fields play a significant role in determining the angular momentum distribution in star-forming cores. In the star formation process, the magnetic fields suppress disc formation. Some researchers pointed out that no disc appears in the early star formation phase, because the disc angular momentum is excessively transferred by the magnetic effect (the so-called magnetic braking catastrophe problem; Mellon & Li 2008). There is another issue to the effect of magnetic fields during the star formation process (the so-called magnetic flux problem). The magnetic flux of a star-forming core is approximately five orders of magnitude greater than that of a protostar (e.g. Nakano 1984). Because magnetic flux is a conserved quantity, the magnetic field should dissipate during the course of the star formation.
The magnetic field is coupled with charged particles, and the amount of charged particles is considerably less in star-forming clouds due to their low temperature and high density. However, during the early gas collapse phase, which is associated with a number density of |$n\lesssim 10^{10}\, {\rm cm}^{-3}$|, the magnetic field is closely coupled to the neutral gas as a result of efficient momentum exchange between charged particles and neutral species. Conversely, as the cloud density increases, dust grains absorb charged particles and the momentum exchange becomes inefficient (Umebayashi & Nakano 1980). Therefore, the magnetic field cannot couple with neutral species and the magnetic field dissipates to a greater extent (Nakano, Nishi & Umebayashi 2002). The magnetic dissipation helps disc formation, because the magnetic braking, which suppresses the formation and evolution of the disc, is alleviated by the dissipation. Thus, the magnetic field and its dissipation are related to major issues (magnetic braking catastrophe and magnetic flux problems) of the star formation process.
Both the degree of ionization (that is, the abundance of charged particles) and the extent of magnetic dissipation during star formation had been investigated in detail using one-zone calculations by Nakano and his collaborators for approximately three decades (Umebayashi & Nakano 1990). The methodology of this group is well established and is frequently applied to estimate the abundance of various chemicals as well as magnetic dissipation during the star formation process (e.g. Tsukamoto et al. 2017; Wurster, Bate & Price 2018b).
Beginning in the 1990s and subsequent to the introduction of the one-zone calculations, which basically estimate the chemical abundance of each charged species, multidimensional magnetohydrodynamics (MHD) simulations of collapsing star-forming clouds were reported. In this process, calculations are performed until a protostar begins to form from the prestellar cloud core stage. One pioneering work by Tomisaka (1998, 2000, 2002) investigated cloud evolution up to the point of protostar formation using two-dimensional ideal MHD simulations. There are three non-ideal MHD effects: Ohmic dissipation, ambipolar diffusion, and the Hall effect. Machida, Inutsuka & Matsumoto (2006, 2007) first calculated protostar formation using non-ideal MHD simulations, although only Ohmic dissipation was considered. Duffin & Pudritz (2009) performed three-dimensional non-ideal MHD simulations including only ambipolar diffusion and showed the early formation of outflow and disc. Subsequently, Tsukamoto et al. (2015a) and Tomida, Okuzumi & Machida (2015) included ambipolar diffusion in addition to Ohmic dissipation.
However, until recently, the Hall effect has been ignored in multidimensional core collapse simulations because it is believed to be not directly related to the magnetic flux problem. It should also be noted that, although both Ohmic dissipation and ambipolar diffusion substantially reduce the magnetic flux in the star-forming core, the Hall effect only changes the magnetic field direction to generate toroidal magnetic fields from global poloidal fields (Wardle & Ng 1999).
Recently, the Hall effect has been considered with regard to the formation and evolution of circumstellar discs (Krasnopolsky, Li & Shang 2011; Tsukamoto et al. 2015b, 2017; Wurster, Price & Bate 2016). Krasnopolsky et al. (2011) have reported that, without rotation, a toroidal magnetic field component that is decoupled from the neutral gases is generated by the Hall effect. In the case that coupling between the magnetic field (or charged particles) and neutral species is recovered, the toroidal field (or twisted magnetic field) imparts a rotation to the infalling gas as a result of magnetic tension. In summary, even when the initial prestellar cloud has no rotation, rotation can be induced by the Hall effect. It should be noted that when a rotation motion is induced by the Hall effect, the magnetic field produces an counter-rotation in a star-forming core due to the angular momentum conservation law, in which the angular momentum of the antirotation is transferred to the outer envelope from the cloud centre by the Alfvén wave. In other words, both clockwise and anticlockwise rotations coexist in the initially non-rotating cloud, as reported by past studies (Krasnopolsky et al. 2011; Tsukamoto et al. 2015b; Wurster et al. 2016; Tsukamoto et al. 2017; Marchand, Commerçon & Chabrier 2018). Thus, it is important to consider the Hall effect when examining the angular momentum problem and the formation and evolution of the circumstellar disc during the star formation process. Note that we should not ignore the Hall effect even when considering the dissipation of magnetic fields (i.e. the magnetic flux problem). Since the Hall effect changes the configuration of the magnetic field, it would affect the dissipation process of the magnetic field (Bai & Stone 2017).
Wardle & Ng (1999) also pointed out that the Hall effect (or Hall conductivity) strongly depends on the chemical abundance, which in turn is determined by the properties of the dust in the star formation process and the ionization (that is, cosmic ray) rate. Thus, it is important to estimate the effect of the Hall conductivity (or Hall coefficient) in conjunction with various grain sizes and cosmic ray rates and, for this purpose, some previous studies have examined grain size ranges and various cosmic ray rates. Hirashita & Lin (2018) investigated the grain sizes in galaxy haloes using the extent of cosmic extinction of distant background quasars, and found that the most likely size range is 0.01–0.3 |$\rm {\mu m}$|. In addition, based on theoretical and observational studies, cosmic ray rates have been estimated to be |$2 \times 10^{-16} \ \rm {s^{-1}}$|(Padovani, Galli & Glassgold 2009) and |$3.4 \times 10^{-18} \ \rm {s^{-1}}$| (Farquhar, Millar & Herbst 1994) in a diffuse core and in the Bok globule B335, respectively. Thus, it is necessary to consider a wide range of possible grain sizes and cosmic ray rates.
However, it is quite difficult to perform multidimensional simulations of cloud collapse including non-ideal MHD effects and incorporating different dust properties and cosmic ray rates because of the limited CPU resources. For example, the calculation time of the simulation including the Hall effect is about 10 times longer than that of the simulation not including the Hall effect, because the whistler waves, which are the right-handed waves induced by the Hall term, should be resolved and implicit methods cannot be applied to the Hall effect (Tsukamoto et al. 2015b). In addition, calculations regarding the formation and evolution of circumstellar discs that resolve the protostar using multidimensional non-ideal MHD simulations have yet to be realized. It is important to note that erroneous results tend to be produced when introducing a sink method to model the long-term evolution of the circumstellar disc (Machida, Inutsuka & Matsumoto 2014). Also, performing calculations to resolve both a protostar and circumstellar disc having large resistivities (or small conductivities) requires exceedingly short time-steps during simulations (Vaytet et al. 2018), and so such calculations cannot be executed. Multidimensional calculations up to the point of several years after protostar formation are possible without employing a sink (e.g. Tomida et al. 2015; Masson et al. 2016; Tsukamoto et al. 2017; Tsukamoto et al. 2018; Wurster, Bate & Price 2018a), but it is important to keep in mind that a sink can introduce numerical artefacts and these should be carefully considered, as discussed in Bate (1998), Machida, Inutsuka & Matsumoto (2010), Machida & Matsumoto (2011), and Machida et al. (2014). In addition to the large computational cost and sink problems, there is a further serious problem in non-ideal MHD simulations including the Hall term. Marchand et al. (2018) pointed out that the angular momentum is not conserved after the first core formation in their Hall MHD simulations. Therefore, the disc formation simulation including the Hall term is not an easy task.
In this study, we analytically estimated the influence of the Hall effect on the formation and evolution of a circumstellar disc. In particular, we focused on the dependence of the Hall coefficient on the grain size (distribution) and the cosmic ray rate. We initially calculated the fractional abundance of charged species by solving chemical networks in conjunction with the grain size (distribution) and cosmic ray strength as input parameters, and derived the Hall coefficient in a realistic parameter space. Then, using the Hall coefficient, we estimated the disc size. On this basis, we discuss the importance of the Hall effect with regard to the disc evolution.
The remainder of this paper is organized as follows. In Section 2, we describe the method used to calculate the Hall coefficient, while in Section 3 we describe the chemical abundance and Hall coefficient results obtained in association with various grain sizes (distributions) and cosmic ray strengths. In Section 4, we describe the disc model obtained by considering the Hall effect and the resulting disc sizes based on the parameters employed. In Section 5, we discuss the time-scale for the Hall effect and the effect of the magnetic field strength. Finally, a summary is presented in Section 6.
2 CHEMICAL REACTIONS AND HALL COEFFICIENT
2.1 The Hall effect and Hall drift velocity
Assuming only uniform vertical magnetic fields in the initial state, the toroidal component of the magnetic field is continuously amplified by the Hall effect until |${\boldsymbol v}=-{\boldsymbol v}_{\rm Hall}$| is realized. Thus, the Lorentz force changes the gas velocity unless the condition |${\boldsymbol v}+{\boldsymbol v}_{\rm Hall}=0$| is fulfilled, and the generation of the toroidal field gradually decreases as the gas velocity, |${\boldsymbol v}$|, approaches |$-{\boldsymbol v}_{\rm Hall}$|. Finally, further generation of the toroidal field is completely suppressed and the gas has a velocity of |${\boldsymbol v}=-{\boldsymbol v}_{\rm Hall}$|, such that the right-hand side of equation (3) becomes zero. The time-scale for the gas velocity to reach |${\boldsymbol v}=-{\boldsymbol v}_{\rm Hall}$| is discussed in Section 5.2.1.
The gas fluid should have a rotational velocity of |${\boldsymbol v}=-{\boldsymbol v}_{\rm Hall}$| without the initial cloud rotation. That is, even in the absence of rotation of the initial cloud, a rotational motion will result from the Hall effect (Krasnopolsky et al. 2011; Tsukamoto 2016; Marchand et al. 2018).
2.2 The Hall coefficient
2.3 Grain size distribution
In this study, we considered four MRN distribution models having different values of amin and amax along with six single-sized grain models. The minimum and maximum radii in each MRN dust grain model (s1a, s1b, s1c, and s2) are provided in Table 1, along with the grain radii for the single-sized models (s3–s8). The dust-to-gas ratio and total dust grains surface area for each model are presented in the sixth and seventh columns of the table, respectively.
Model . | amin (|$\rm {\mu m}$|) . | asingle (|$\rm {\mu m}$|) . | amax (|$\rm {\mu m}$|) . | smax . | fdg . | σtot/nH (|$\rm {cm^5}$|) . |
---|---|---|---|---|---|---|
s1a | 0.005 | 0.25 | 10 | 0.01 | 2.830 52 × 10−21 | |
s1b | 0.005 | 0.25 | 10 | 0.005 | 1.415 26 × 10−21 | |
s1c | 0.005 | 0.25 | 10 | 0.02 | 5.661 05 × 10−21 | |
s2 | 0.0181 | 0.9049 | 10 | 0.0341 | 2.666 49 × 10−21 | |
s3 | 0.3 | 1 | 0.01 | 5.835 31 × 10−22 | ||
s4 | 0.1 | 1 | 0.01 | 1.744 86 × 10−21 | ||
s5 | 0.075 | 1 | 0.01 | 2.336 44 × 10−21 | ||
s6 | 0.05 | 1 | 0.01 | 3.5035 × 10−21 | ||
s7 | 0.025 | 1 | 0.01 | 7.000 06 × 10−21 | ||
s8 | 0.01 | 1 | 0.01 | 1.744 86 × 10−20 |
Model . | amin (|$\rm {\mu m}$|) . | asingle (|$\rm {\mu m}$|) . | amax (|$\rm {\mu m}$|) . | smax . | fdg . | σtot/nH (|$\rm {cm^5}$|) . |
---|---|---|---|---|---|---|
s1a | 0.005 | 0.25 | 10 | 0.01 | 2.830 52 × 10−21 | |
s1b | 0.005 | 0.25 | 10 | 0.005 | 1.415 26 × 10−21 | |
s1c | 0.005 | 0.25 | 10 | 0.02 | 5.661 05 × 10−21 | |
s2 | 0.0181 | 0.9049 | 10 | 0.0341 | 2.666 49 × 10−21 | |
s3 | 0.3 | 1 | 0.01 | 5.835 31 × 10−22 | ||
s4 | 0.1 | 1 | 0.01 | 1.744 86 × 10−21 | ||
s5 | 0.075 | 1 | 0.01 | 2.336 44 × 10−21 | ||
s6 | 0.05 | 1 | 0.01 | 3.5035 × 10−21 | ||
s7 | 0.025 | 1 | 0.01 | 7.000 06 × 10−21 | ||
s8 | 0.01 | 1 | 0.01 | 1.744 86 × 10−20 |
Model . | amin (|$\rm {\mu m}$|) . | asingle (|$\rm {\mu m}$|) . | amax (|$\rm {\mu m}$|) . | smax . | fdg . | σtot/nH (|$\rm {cm^5}$|) . |
---|---|---|---|---|---|---|
s1a | 0.005 | 0.25 | 10 | 0.01 | 2.830 52 × 10−21 | |
s1b | 0.005 | 0.25 | 10 | 0.005 | 1.415 26 × 10−21 | |
s1c | 0.005 | 0.25 | 10 | 0.02 | 5.661 05 × 10−21 | |
s2 | 0.0181 | 0.9049 | 10 | 0.0341 | 2.666 49 × 10−21 | |
s3 | 0.3 | 1 | 0.01 | 5.835 31 × 10−22 | ||
s4 | 0.1 | 1 | 0.01 | 1.744 86 × 10−21 | ||
s5 | 0.075 | 1 | 0.01 | 2.336 44 × 10−21 | ||
s6 | 0.05 | 1 | 0.01 | 3.5035 × 10−21 | ||
s7 | 0.025 | 1 | 0.01 | 7.000 06 × 10−21 | ||
s8 | 0.01 | 1 | 0.01 | 1.744 86 × 10−20 |
Model . | amin (|$\rm {\mu m}$|) . | asingle (|$\rm {\mu m}$|) . | amax (|$\rm {\mu m}$|) . | smax . | fdg . | σtot/nH (|$\rm {cm^5}$|) . |
---|---|---|---|---|---|---|
s1a | 0.005 | 0.25 | 10 | 0.01 | 2.830 52 × 10−21 | |
s1b | 0.005 | 0.25 | 10 | 0.005 | 1.415 26 × 10−21 | |
s1c | 0.005 | 0.25 | 10 | 0.02 | 5.661 05 × 10−21 | |
s2 | 0.0181 | 0.9049 | 10 | 0.0341 | 2.666 49 × 10−21 | |
s3 | 0.3 | 1 | 0.01 | 5.835 31 × 10−22 | ||
s4 | 0.1 | 1 | 0.01 | 1.744 86 × 10−21 | ||
s5 | 0.075 | 1 | 0.01 | 2.336 44 × 10−21 | ||
s6 | 0.05 | 1 | 0.01 | 3.5035 × 10−21 | ||
s7 | 0.025 | 1 | 0.01 | 7.000 06 × 10−21 | ||
s8 | 0.01 | 1 | 0.01 | 1.744 86 × 10−20 |
2.4 Chemical reactions and networks
Calculation of the Hall coefficient also required determination of the fractional abundance of each charged species, xν (see equations 10 and 11). In this subsection, we describe the method by which the chemical abundance of each charged particle was determined, based on a series of papers by Umebayashi & Nakano (1990). In these calculations, the relative abundance of each neutral species (H2, He, CO, O2, O, and Mg) relative to the number of hydrogen atoms was fixed as shown in Table 2.
Abundance of each neutral species relative to the number of hydrogen atoms (Sano et al. 2000). δ indicates the fraction of each element remaining in the gas phase. The fractional abundances of molecules, δm, and of metal ions, δM, in the interstellar gas phase are δm = 0.2 and δM = 0.02, respectively, while the abundance of oxygen molecules in the gas phase is δO2 = 0.7 (Morton 1974).
Chemical species . | Relative abundances . |
---|---|
|$\rm {H_2}$| | x|$\rm {H_2} = 0.5$| |
He | xHe = 9.75 × 10−2 |
CO | xCO = 3.62 × 10−4 δm |
|$\rm {O_2}$| | x|$\rm {O_2}$| = 0.5 δO2 (8.53 − 3.62) × 10−4δm |
O | |$\rm {xO} = (1-\delta {\rm O}_2) (8.53-3.62) \times 10^{-4} \delta {\rm m}$| |
Mg | xMg = 7.97 × 10−5δM |
Chemical species . | Relative abundances . |
---|---|
|$\rm {H_2}$| | x|$\rm {H_2} = 0.5$| |
He | xHe = 9.75 × 10−2 |
CO | xCO = 3.62 × 10−4 δm |
|$\rm {O_2}$| | x|$\rm {O_2}$| = 0.5 δO2 (8.53 − 3.62) × 10−4δm |
O | |$\rm {xO} = (1-\delta {\rm O}_2) (8.53-3.62) \times 10^{-4} \delta {\rm m}$| |
Mg | xMg = 7.97 × 10−5δM |
Abundance of each neutral species relative to the number of hydrogen atoms (Sano et al. 2000). δ indicates the fraction of each element remaining in the gas phase. The fractional abundances of molecules, δm, and of metal ions, δM, in the interstellar gas phase are δm = 0.2 and δM = 0.02, respectively, while the abundance of oxygen molecules in the gas phase is δO2 = 0.7 (Morton 1974).
Chemical species . | Relative abundances . |
---|---|
|$\rm {H_2}$| | x|$\rm {H_2} = 0.5$| |
He | xHe = 9.75 × 10−2 |
CO | xCO = 3.62 × 10−4 δm |
|$\rm {O_2}$| | x|$\rm {O_2}$| = 0.5 δO2 (8.53 − 3.62) × 10−4δm |
O | |$\rm {xO} = (1-\delta {\rm O}_2) (8.53-3.62) \times 10^{-4} \delta {\rm m}$| |
Mg | xMg = 7.97 × 10−5δM |
Chemical species . | Relative abundances . |
---|---|
|$\rm {H_2}$| | x|$\rm {H_2} = 0.5$| |
He | xHe = 9.75 × 10−2 |
CO | xCO = 3.62 × 10−4 δm |
|$\rm {O_2}$| | x|$\rm {O_2}$| = 0.5 δO2 (8.53 − 3.62) × 10−4δm |
O | |$\rm {xO} = (1-\delta {\rm O}_2) (8.53-3.62) \times 10^{-4} \delta {\rm m}$| |
Mg | xMg = 7.97 × 10−5δM |
As described in Section 2.2, |$\rm {{H_3}^+,m^+,Mg^+,He^+,C^+, and \ H^+}$| were considered as the charged species in addition to the charged dust grains (see below), where m+ represents molecular ions other than |${\rm H_3^+}$|. Because the most abundant charged molecular ion species is HCO+, we identified m+ with HCO+ (Marchand et al. 2016). A total of 25 chemical reactions was considered.
The four types of charged particle reactions incorporated in the calculations were
|$\rm {j \rightarrow i+e^{-}}$| (ionization of neutral particles),
|$\rm {i + e^{-} \rightarrow j}$| (recombination of positive ions and electrons),
|$\rm {i + k \rightarrow j+ \ast}$| (recombination of charged ions), and
|$\rm {G({\it q})+ i/e^- \ ({\rm ion \ or \ electron}) \rightarrow G({\it q} \pm 1)}$| (absorption of charged particles on to dust grains following collisions).
Here, i indicates a charged species, j and k represent different neutral species, * is the product of a charged species, and G(q) is dust having charge q. In the following discussions, for convenience, we assign a number to each charged particle (ion or electron), as shown in Table 3.
Species . | Assigned number i . |
---|---|
e− | 0 |
H|$_3^+$| | 1 |
m+ | 2 |
Mg+ | 3 |
He+ | 4 |
C+ | 5 |
H+ | 6 |
Species . | Assigned number i . |
---|---|
e− | 0 |
H|$_3^+$| | 1 |
m+ | 2 |
Mg+ | 3 |
He+ | 4 |
C+ | 5 |
H+ | 6 |
Species . | Assigned number i . |
---|---|
e− | 0 |
H|$_3^+$| | 1 |
m+ | 2 |
Mg+ | 3 |
He+ | 4 |
C+ | 5 |
H+ | 6 |
Species . | Assigned number i . |
---|---|
e− | 0 |
H|$_3^+$| | 1 |
m+ | 2 |
Mg+ | 3 |
He+ | 4 |
C+ | 5 |
H+ | 6 |
In the case of reaction (1), cosmic rays represent the ionization source. Here, the parameter ζ is applied, equal to the total ionization rate of a hydrogen molecule, and we set the reaction rate of |$\rm {H_2}$| and He as shown in table 2 in Umebayashi & Nakano (1990). The cosmic ray rates employed in this study are provided in Table 4, with ζ = 10−17 s−1 as the fiducial value.
. | . | ζ ( s−1 ) . | . | . |
---|---|---|---|---|
10−18 | 10−17.5 | 10−17 | 10−16.5 | 10−16 |
. | . | ζ ( s−1 ) . | . | . |
---|---|---|---|---|
10−18 | 10−17.5 | 10−17 | 10−16.5 | 10−16 |
. | . | ζ ( s−1 ) . | . | . |
---|---|---|---|---|
10−18 | 10−17.5 | 10−17 | 10−16.5 | 10−16 |
. | . | ζ ( s−1 ) . | . | . |
---|---|---|---|---|
10−18 | 10−17.5 | 10−17 | 10−16.5 | 10−16 |
The chemical reactions and the associated reaction rates in points (2) and (3), above, are taken from the UMIST database (McElroy et al. 2013) and are summarized in Table A1 in Appendix A.
Since dust grains absorb charged particles, they play a significant role in determining the fractional abundances of such particles. In addition, because the dust grains themselves are charged, they also contribute to the Hall coefficient. In Appendix B, we discuss reaction (4), which is based on collisions between dust grains and charged particles with subsequent absorption of the charged particles on the grain surfaces.
At this point, we explain the calculations used to derive the abundances of charged particles and dust grains. For the sake of convenience, these calculations are based on the abundance of charged particles and dust grains relative to the number of hydrogen atoms, and so the abundances of each charged species and dust grain is described as xi = ni/nH and xd = nd/nH. In this process, the maximum and minimum charges of the dust grains at each gas density are determined (for details, see Okuzumi 2009), and the time-derivative equation for each species is provided in Appendix C. The fractional abundance of each charged particle and dust grain as a function of the gas density was calculated according to the following procedure:
beginning from the initial chemical abundance values in Table 2, the equations given in Appendix C were implicitly solved for a fixed gas density and gas temperature (see Section 2.5) until an equilibrium state was realized, and the initial dust grains abundance values were pre-calculated for each dust distribution model (using equation 22 for MRN models and equation 24 for single-sized models), following which
the gas density was increased by 0.1 dex and step (a) was repeated.
Using this procedure, the fractional abundance of each species was derived over the range of |$10^4\, {\rm cm}^{-3} \lt n_{\rm H} \lt 10^{14}\, {\rm cm}^{-3}$|. It should be noted that we confirmed that the elapsed time required to obtain an equilibrium state was much shorter than the freefall time-scale tff (= |$(3\pi /(32\, G\, \rho))^{1/2}$|) in the density range considered in this study. We compare the elapsed time-scale and freefall time-scale and show that equilibrium time is much shorter than freefall time in Appendix D. Finally, using the abundance of each species and the equations described in Section 2.2, we derived the Hall coefficient, ηH, for each gas density. Employing 10 different dust grain models (Table 1) and five different cosmic ray rates (Table 4), we calculated the chemical abundance values and the Hall coefficients for 50 models in total.
2.5 Gas temperature and magnetic field strength
Fig. 1 plots the gas temperatures (left) derived from equation (26) and the magnetic field strengths (right) derived from equation (30) with β = 100 against the number density. These plots are in good agreement with recently published one-dimensional and multidimensional simulations (Tomida et al. 2015 ;Tsukamoto et al. 2015a).

Gas temperature (left) and magnetic field strength (right) as functions of number density.
3 RESULTS OF CHEMICAL REACTION CALCULATIONS
Chemical reactions were calculated according to the method outlined in Section 2. To begin with, we present the chemical abundance results obtained using different dust models in conjunction with ζ = 10−18 (Fig. 2), 10−17 (Fig. 3), and 10−16 s−1 (Fig. 4). These data indicate that the chemical abundances are significantly affected by both the dust distribution and cosmic ray rate. As the grain size becomes smaller, the adsorption of charge on to the grains becomes more effective, such that the number of ions and electrons decreases, as shown in Fig. 3. In addition, we checked the relation between the number of grains and fdg comparing models s1a, s1b, and s1c, and confirmed that the fractional abundances of grains increase as fdg decreases. Figs 2–4 also show that the fractional abundances of dust grains in single-sized models s3–s8 are roughly proportional to a−3 because the total mass of grains is fixed. Models s1a and s7 in Fig. 3 give similar results because the average size in MRN model s1a is 0.035|$\,\rm {\mu m}$| (as calculated using equation 20), which is close to the grain size assumed in model s7 (0.025 μm). In contrast, models s3 (asingle = 0.3 μm) and s8 (asingle = 0.01 μm) provide noticeably different results, with the abundances of Mg+ and e− at |$n_{\rm H}=10^8\, {\rm cm}^{-3}$| from model s3 being two and four orders of magnitudes higher, respectively, than those from model s8. These large differences in the fractional abundances of charged species greatly affects the Hall coefficient. In addition, a comparison of Figs 2, 3, and 4 shows that the cosmic ray ionization rate significantly affects the fractional abundances of charged particles. To a first approximation, the fractional abundances of charged particles scale linearly with the ionization rate.

Chemical abundances of charged species, neutral species, and charged dust grains (Z = ±1) for different dust models (s1a, s3, s4, s5, s7, and s8), obtained using a constant ionization rate of ζ = 10−18 s−1, as functions of the number density.

The same data as in Fig. 2 but for |$\zeta =10^{-17} \rm {s^{-1}}$| using models (s1a, s3, s4, s5, s7, and s8).

The same data as in Fig. 2 but for |$\zeta =10^{-16}\, \rm {s^{-1}}$| using models (s1a, s3, s4, s5, s7, and s8).
Figs 5 and 6 show the Hall coefficients calculated for the different dust models using equations (5)–(16). These plots indicate that the absolute value of the Hall coefficient is modified by both the grain size and grain size distribution, as well as by the cosmic ray strength. Furthermore, as seen in Figs 5 and 6, the sign of the Hall coefficient can change depending on the grain size or grain size distribution. As an example, in the centre panel of Fig. 5 (ζ = 10−17 s−1), the Hall coefficient is positive over the entire range of |$10^4\, {\rm cm}^{-3} \lesssim n_{\rm H} \lesssim 10^{14}\, {\rm cm}^{-3}$| for model s3, while it is positive only in the range of |$n_{\rm H} \gt 10^{13}\, {\rm cm}^{-3}$| for model s5. Thus, even a change in the grain size by a factor of 4 can cause a flip in the sign of the Hall coefficient at |$n_{\rm H} \sim 10^{13}\, {\rm cm}^{-3}$|. Zhao, Caselli & Li (2018) also showed that large-sized grains (or removal of small-sized grains; |${\lesssim } 0.1\, \rm {\mu m}$|) noticeably decrease the Hall coefficient, which agrees well with our results (see the centre panel of Fig. 5).

Hall coefficients for single-sized dust models at ζ = 10−18 (left), 10−17 (centre), and 10−16 s−1 (right). The results from models s3, s4, s5, s6, s7, and s8 are plotted in blue, red, green, yellow, orange, and purple. For each line, the positive and negative values of ηH are indicated by broken and solid lines, respectively.

Hall coefficients for various MRN dust distributions. Models s1a, s1b, s1c, s2, and s4 are plotted in green, light green, dark green, grey, and red, respectively. For each line, positive and negative values of ηH are indicated by solid and broken lines, respectively.
4 APPLICATION: DISC SIZE INDUCED BY THE HALL EFFECT
As described in Section 1, the purpose of this study was to estimate the disc size considering solely the Hall effect. To correctly determine the disc size, non-ideal MHD simulations were required (e.g. Tsukamoto et al. 2015b). However, during the star formation process, a small disc formed around a protostar gradually evolves. Thus, at minimum, the spatial scale of the protostar should be resolved (Vaytet et al. 2018) when examining the formation and evolution of the circumstellar disc. Despite this, the time-scale becomes extremely short when resolving the protostar, and so it is impossible to simulate disc evolution and determine the disc size with adequate spatial resolution. As an example, a very recent simulation managed to calculate the disc evolution over a time span of several months following protostar formation (e.g. Tomida et al. 2015; Masson et al. 2016; Tsukamoto et al. 2017). In contrast, observations have indicated that the main accretion phase, during which the disc evolves via mass accretion, lasts for ∼105 yr (Andre & Montmerle 1994; Enoch et al. 2008). In addition, the Hall coefficient, which is related to the angular momentum associated with transport in the infalling gas and disc evolution, is greatly affected by specific dust properties and the environmental effects of the ionization source (or the cosmic ray strength). Thus, to determine the disc size, it is necessary to calculate the disc evolution over a span of at least ∼105 yr, while resolving the protostar using the grain size and cosmic ray strength as parameters. Since such calculations are difficult to execute even using the fastest supercomputers presently available, we analytically estimated the disc size by referring to the simulation results.
Because the Hall coefficient is determined by the abundance of charged particles, the charged particle properties and chemical networks were discussed in the previous sections. Below, in order to simplify our assumptions, we estimate and discuss the influence of the Hall effect on the evolution and formation of the circumstellar disc. This discussion begins with an explanation of the process used to estimate the disc size induced by the Hall effect.
The (specific) angular momentum of the infalling gas resulting from the Hall effect must first be evaluated, as this determines the disc size. Note that the angular momentum is redistributed in the disc and a part of the angular momentum is also ejected by protostellar outflow, meaning that the estimates provided herein actually refer to the upper limit of the disc size. Even so, it is useful to assess the effects of both the dust properties and cosmic ray strength on the Hall coefficient and resultant disc size. Our approach to estimating the disc size is illustrated schematically in Fig. 7. To begin, we assume a non-rotating prestellar cloud. Although this assumption is not actually correct, it is a useful approach to estimating the angular momentum resulting solely from the Hall effect. Next, we calculate the chemical networks and derive the Hall coefficient as a function of cloud density, which can be converted to a length-scale (or Jeans length). Subsequently, the angular momentum of the infalling gas is derived by defining rHall and assuming that the infalling gas instantaneously acquires the angular momentum at rHall. In this study, we use the term rHall for the Hall radius or Hall point and employ a value of rHall = 300 au, which is similar to the pseudo-disc size (Tsukamoto et al. 2017). A Jeans length of rHall = 300 au corresponds to a number density of nHall = 108 cm−3.

Even without rotation, the magnetic field is twisted by the Hall effect such that a toroidal component is produced. Subsequently, after coupling between the neutral gas and magnetic field (or charged particles) is recovered, the magnetic tension force caused by the toroidal component of the magnetic field imparts a rotational motion. This is the reason why the non-rotating gas acquires an angular momentum as a result of the Hall effect.
4.1 Hall velocity
4.2 Disc model and angular momentum estimated using the Hall effect
As described above, the disc surface density is determined based on the Q-parameter. However, since disc fragmentation may occur when Q ≲ 1, it is difficult to retain a simple disc. Thus, we consider that csd = 1 (i.e. Q = 1) gives the maximum surface density. In reality, because the disc surface density is expected to be less than csd = 1, csd is parametrized and the value adopted in this study is provided in Table 5. The protostellar mass, which is also employed as a parameter to determine the disc radius, is included in the same table.
csd . | 1, 0.1, 0.01 . |
---|---|
Mstar (M⊙) | 0.03, 0.05, 0.07, 0.1, 0.3, 0.5, 0.7 |
csd . | 1, 0.1, 0.01 . |
---|---|
Mstar (M⊙) | 0.03, 0.05, 0.07, 0.1, 0.3, 0.5, 0.7 |
csd . | 1, 0.1, 0.01 . |
---|---|
Mstar (M⊙) | 0.03, 0.05, 0.07, 0.1, 0.3, 0.5, 0.7 |
csd . | 1, 0.1, 0.01 . |
---|---|
Mstar (M⊙) | 0.03, 0.05, 0.07, 0.1, 0.3, 0.5, 0.7 |
4.3 Keplerian disc induced by the Hall effect
The disc size induced by the Hall effect was determined according to the procedure:
the protostellar mass, Mstar, was assumed to determine the total mass, Mtot (equation 42),
the specific angular momentum, |$j_{\rm Hall}= r_{\rm Hall}\, v_{\rm Hall, \phi}$|, was estimated using equation (36),
the total angular momentum of the accreted material was calculated as |$J_{\rm Hall}=M_{\rm tot}\, j_{\rm Hall}$|,
the total angular momentum of the Keplerian disc was estimated based on equation (44), assuming that the disc extends to a very large radius, and
the disc size, rdisc, at which the angular momentum of the Keplerian disc equals that of the accreted material [the rotation of which is determined by the Hall effect as in steps (i)–(ii)] was determined.
After varying the protostellar mass, steps (i)–(v) were repeated using the different models listed in Tables 1 and 4, to determine rdisc for each model. The resulting values are presented in Fig. 8 as filled magenta circles. As an example of the estimation of the disc induced by the Hall effect, Fig. 8 plots the angular momentum values for Keplerian and Hall discs (hereafter, we refer to discs formed by the Hall effect as Hall discs). These values were obtained using csd = 1 and ζ = 10−17 s−1 for different grain size models and assuming a protostellar mass of |$M_{\rm star}=0.1\, \mathrm{ M}_\odot$|. Additionally, the specific angular momentum induced by the Hall effect, jHall, was calculated for each model (see Section 4.2). For each line (that is, each grain size model) in this figure, the angular momentum of the Hall disc is less than that of the Keplerian disc outside the point denoted by the purple circle, meaning that a rotationally supported disc will not form in such regions. Conversely, in the region (or at the radius) inside the purple circle, the angular momentum of the Hall disc is greater than that of the Keplerian disc and so a rotationally supported disc (i.e. a Keplerian disc) can form. Because angular momentum can be transferred inside the disc, it is difficult to precisely determine the disc radius values in this study. Even so, a comparison of the angular momenta of the Hall disc and the Keplerian disc allows a rough estimation of the disc size for a given grain size and protostellar mass. The data in this figure indicate that the disc size is rdisc = 2.13 au in the case of model s4 (|$a_{\rm single}=0.1\, {\rm \mu m}$|) and 5.01 au in the case of model s8 (|$a_{\rm single}=0.01\, {\rm \mu m}$|).

The angular momentum values of the Hall discs for different grain size models versus the radius, as obtained using csd = 1 and ζ = 10−17 s−1, with a protostellar mass of |$M_{\rm star}=0.1\, \mathrm{ M}_\odot$|. The thick black solid line corresponds to the angular momentum of the Keplerian disc. The filled magenta circles indicate the intersections of the angular momenta of Hall and Keplerian discs, and correspond to the radii of the Hall discs.
While varying the protostellar mass, Mstar, we derived the corresponding disc sizes according to the procedure described above. Fig. 9 plots the disc sizes obtained using the single-sized (left) and MRN (right) dust grain size distribution models as functions of the protostellar mass, based on using csd = 1 and ζ = 10−17 s−1. These plots demonstrate that the size of the Keplerian disc varies considerably depending on the grain size (distribution), even if the protostellar mass is kept constant. As an example, at |$M_{\rm ps}=0.7\, \mathrm{ M}_\odot$|, the disc size for asingle = 0.025 μm (model s7) is rdisc = 80 au, while the size for 0.3 μm (model s3) is rdisc = 3 au (left-hand panel of Fig. 9), corresponding to a variation in the disc size by a factor of 27. This result indicates that both the Hall effect and dust properties can affect the formation and evolution of the circumstellar disc.

Disc sizes obtained using single-sized (left) and MRN (right) grain distributions as functions of the protostellar mass, as calculated with csd = 1 and ζ = 10−17 s−1.
4.4 Parameter effects
The effects of the various parameters on the size of the Keplerian disc induced by the Hall effect were examined by constructing a fiducial model with the surface density parameter csd = 1, protostellar mass Mstar = 0.1 M⊙ and a cosmic ray ionization rate of ζ = |$10^{-17} \rm {s^{-1}}$|. In this subsection, we discuss the results.
Fig. 10 plots the disc sizes as functions of csd for each dust model listed in Tables 1 and 5, obtained using a protostellar mass of |$M_{\rm star}=0.1\, \mathrm{ M}_\odot$| and an ionization rate of ζ = |$10^{-17} \rm {s^{-1}}$|. As described in Section 4.2, we constructed the disc model on the basis of Q = 1, which corresponds to a marginally gravitationally unstable disc. Subsequently, we calculated the disc sizes, while adjusting the disc surface density using the parameter csd. As can be seen from these data, the disc size increases as the disc surface density decreases. This occurs because a less massive disc requires a large radius to have the same angular momentum as a more massive disc. However, the disc size is not strongly correlated with the surface density or with csd. As demonstrated by Fig. 10, the disc radius increases by approximately one order of magnitude when the disc surface density is reduced by about two orders of magnitude (csd = 0.01).

Disc sizes obtained from the single-sized (left) and MRN (right) dust grain distributions versus the disc surface density control parameter csd, obtained using a prestellar mass of |$M_{\rm star}=0.1\, \mathrm{ M}_\odot$| and a cosmic ray ionization rate of ζ = 10−17 s−1.
Fig. 11 summarizes the effect of the cosmic ray ionization rate ζ on the disc size for different grain size models. Basically, the disc size decreases as ζ increases, because the non-ideal effect (or the Hall effect) becomes ineffective in an environment in which the ionization intensity is strong. However, an exception is also evident such that, in the case of the small dust grain models (models s1a, s1c and s8), a disc radius peak is seen in the vicinity of ζ ∼ 10−17.5–10−16.5 s−1. These three models have greater proportions of small dust particles than the other seven models (as seen in Table 1) along with a smaller proportion of electrons, and the peak is attributed to these differences. The calculations required to obtain the Hall coefficient are highly complex and so at present we cannot conclusively identify the cause of the peak. However, this phenomenon will be addressed in a forthcoming paper.

Disc sizes for the single-sized (left) and MRN (right) dust grain distributions as functions of the cosmic ray ionization rate, ζ, obtained using csd = 1 and |$M_{\rm star}=0.1\, \mathrm{ M}_\odot$|.
5 CAVEATS
As reported in Section 2, previous simulation studies have identified the possible importance of the Hall effect during the star formation process. However, long-term simulations (up to the formation of a mature circumstellar disc) cannot be performed because the whistler waves propagating to the star-forming cloud must be resolved using a very short time-steps to properly estimate the Hall effect during simulations (e.g. Sano & Stone 2002). Thus, in this study, we analytically estimated the impact of the Hall effect on disc evolution in star-forming clouds, and found that this effect significantly influences the star and disc formation processes depending on the dust properties and the strength of ionization sources. However, there are some caveats associated with this investigation of the circumstellar disc induced by the Hall effect. In this section, we discuss the validity of the assumptions used in this study.
5.1 Other non-ideal MHD effects
In addition to the Hall effect and ambipolar diffusion, Ohmic dissipation also affects the disc formation (e.g. Machida, Inutsuka & Matsumoto 2011). Moreover, in analytical works, we ignored some mechanisms of angular momentum transfer such as protostellar outflow that significantly reduces the angular momentum of the disc. Thus, in order to fully investigate the disc evolution, we need to execute non-ideal MHD simulations including all the non-ideal MHD terms in future.
5.2 Assumptions and limitations of the disc model
In this subsection, we discuss the assumptions and limitations used in this study. Especially, we focus on the time-scale for convergence of the Hall velocity, the initial rotation, and the size growth of grains.
5.2.1 Convergence time-scale of the Hall velocity
In Section 4.1, we assumed that gas particles instantaneously receive the angular momentum (or the Hall velocity) at the moment at which they pass through the Hall radius (see Section 4.2). In the collapsing cloud, the Hall velocity results from the Lorenz force of the toroidal field component induced by the Hall effect. We assumed the toroidal field produced by the Hall effect at a specific, constant value. However, it is necessary to estimate the saturation time-scale in order to confirm that the gas particles indeed obtain the Hall velocity estimated in Section 4.1.
5.2.2 Initial rotation
In this study, we ignored the rotation of prestellar clouds for simplicity. Observations show that molecular cloud cores have non-negligible rotations or angular momenta (e.g. Goodman et al. 1993; Caselli et al. 2002). Thus, our assumption of non-rotating cores is not very correct. However, we could estimate the angular momentum purely induced by the Hall effect, and found that the Hall effect significantly influences the disc formation. This indicates that the Hall effect cannot be ignored to investigate the disc formation, independent of the initial cloud rotation.
5.2.3 Grain growth during star formation process
We do not include the time-dependent grain growth. However, in reality, grains would grow by collisions between grains or sticking molecules on to grains. In addition, collisional destruction should be occurred in the star-forming cloud.
Chiaki et al. (2014) executed the simulations to estimate the dust growth under very low metallicity environments. They showed that the grain growth can change the star formation process under such environments. Our results showed that the grain sizes strongly affect the Hall effect and resulting disc size. Thus, we require simulations including the time-dependent change of grain sizes (or grain growth) in a future study.
5.3 The effect of magnetic field strength
A value of β = 100 was used to estimate the magnetic field strength in conjunction with equation (30), which is consistent with recent numerical simulations (e.g. Wurster et al. 2018b). However, since only the very early phase of disc formation has been investigated by simulations, the magnetic field strength and plasma beta of the disc would be expected to vary over time.
In this subsection, we assess the effect of the magnetic field strength (or plasma beta) on the disc size. Based on Section 4.2, we again calculated the disc size, employing β values over the range of 1 ≤ β ≤ 500. Fig. 12 plots the disc size values against the plasma beta, as determined using the fiducial parameters asingle = 0.1 μ m and |$\zeta = 10^{-17}\, \rm {s^{-1}}$|. This figure confirms that the disc size decreases as β increases over the range of 1 ≲ β ≲ 50, but increases in the case of β values in the range of β ≳ 50. At |$n_{\rm {Hall}} = 10^8\, \rm {cm^{-3}}$|, the Hall coefficient, ηH, becomes large as the magnetic field is strengthened (see fig. 6 in Marchand et al. 2016). In the present analysis, when 1 ≲ β ≲ 50, variations in ηH are primarily responsible for changes in β . In contrast, when 50 ≲ β ≲ 500, the decrease in the vertical component of the magnetic field, B|$z$|, determines the disc size (see equation 36). However, the dependence of the magnetic field on ηH is not straightforward (see equations 6–9), and thus we cannot provide a simple explanation of the trend seen in Fig. 12. During the star formation process, although the fluctuations in the magnetic field strength are complex, our results suggest that it is important to consider the magnetic field strength when assessing the Hall effect.

It is evident that the disc size varies with the magnetic field strength, and that the magnetic field is accumulated and amplified in the disc because it is coupled with the infalling matter. In contrast, the magnetic field is dissipated by Ohmic dissipation and ambipolar diffusion in the disc, and the magneto-rotational instability plays a role in determining the magnetic field strength in the disc. These effects are beyond the scope of this study, and the determination of magnetic field strength in the disc would not be possible even using state-of-art simulations. The results of this work imply that the magnetic field strength is important for investigating the angular momentum induced by the Hall effect. Thus, both the magnetic field strength and Hall effect would influence the formation and evolution of circumstellar discs.
6 SUMMARY
In this study, we analytically estimated the influence of the Hall effect on the formation and evolution of circumstellar discs. The chemical reactions in the collapsing cloud were initially determined to derive the Hall coefficient based on prior publications, but using a variety of dust grain models and ionization intensities. The results show that the Hall coefficient strongly depends both on the assumed dust model and the ionization intensity.
Subsequently, a simple disc model was employed to evaluate the size of the circumstellar disc solely on the basis of the Hall effect. Depending on the grain size and ionization intensity values selected, disc sizes of ∼3–100 au (∼2–20 au) were obtained for a protostar mass of |$0.5\, \mathrm{ M}_\odot$| (|$0.1\, \mathrm{ M}_\odot$|). It was expected that at nHall = 108 cm−3, which number density is used in the disc model, smaller dust grains tend to form a larger disc in the grain size range of |$0.025\,\rm {\mu }m \lesssim a_{\rm {single}} \lesssim 0.3\,\rm {\mu }m$|, because small grains significantly reduce the fraction of charged particles and amplify the non-ideal MHD effects. Conversely, in the range of |$0.01\,\rm {\mu }m \lesssim a_{\rm {single}} \lesssim 0.025\,\rm {\mu }m$|, the disc size decreases as the grain size becomes smaller, because charged dust grains are much more abundant than charged particles. As such, a peak in the disc size change data appears at |$a_{\rm {single}}=0.025\,\rm {\mu }m$| in the case of |$\zeta =10^{-17} \rm {s^{-1}}$|. In addition, large discs tend to be associated with weak ionization intensities, as a result of coupling between charged species and neutral gas.
The Keplerian discs observed around Class 0 objects have a size of ∼10–100 au, which is comparable to the disc size induced by the Hall effect. Thus, the Hall effect evidently contributes to the disc evolution, depending on the star-forming environment. It is important to note that the simple disc model in the work reported herein was not comprehensive. In particular, the time required for the growth of dust grains was neglected. Nevertheless, this work demonstrates that the Hall coefficient is significantly dependent on the average grain size, and so investigations of disc evolution must take into account the growth of dust particles.
ACKNOWLEDGEMENTS
We thank the referee for his/her useful comments. The authors gratefully acknowledge helpful discussions with K. Tomida. This work was supported by JSPS KAKENHI grants (numbers 17H02869, JP17K05387, JP17H06360, and 17KK0096). This research used computational resources within the high-performance computing infrastructure (HPCI) system provided by the Cyberscience Center, Tohoku University, the Cybermedia Center, Osaka University, and the Earth Simulator, JAMSTEC via the HPCI System Research Project (project numbers hp170047 and hp180001). Simulations were also performed by 2017 and 2018 Koubo Kadai on the Earth Simulator (NEC SX-ACE) at JAMSTEC.
Footnotes
REFERENCES
APPENDIX A: REACTION RATES
All the reactions used in this study, along with the associated reaction rates, are summarized in Table A1. The reaction between a charged particle i (that is, an ion) and an electron, e−, is written as ki, while kij represents the reaction rate between charged species i and neutral species j, as in Table 3. Note that the HCO+ reaction rate was used as the m+ reaction rate, because HCO+ is the most abundant molecular ion after H|$_3^+$|. In the case that a single charged species could undergo multiple reactions, these were distinguished using the symbols a − e. As an example, H|$_3^+$| can participate in five different reactions, with reaction rates k12a, k12b, k12c, k12d, and k12e. As described in Section 2.4, these reaction rates were acquired from the UMIST database (McElroy et al. 2013).
Reaction . | Rate (|$\rm {cm^3\, s^{-1}}$|) . |
---|---|
|$\rm {H_3^+ + e^- \rightarrow H_2 + H}$| | |$k_{1a}=2.34 \times 10^{-8} (\frac{T}{300})^{-0.5}$| |
|$\rm {H_3^+ + e^- \rightarrow H+H+H}$| | |$k_{1b}=4.36 \times 10^{-8} (\frac{T}{300})^{-0.5}$| |
|$\rm {HCO^+ + e^- \rightarrow CO + H}$| | |$k_2=2.4 \times 10^{-7} (\frac{T}{300})^{-0.7}$| |
|$\rm {Mg^+ + e^- \rightarrow Mg}$| + hν | |$k_3=2.78 \times 10^{-12} (\frac{T}{300})^{-0.7}$| |
|$\rm {He^+ + e^- \rightarrow He}$| + hν | |$k_4=5.36 \times 10^{-12} (\frac{T}{300})^{-0.5}$| |
|$\rm {C^+ + e^- \rightarrow C}$| + hν | |$k_5=2.36 \times 10^{-12} (\frac{T}{300})^{-0.3} \rm {exp}(\frac{-17.6}{T})$| |
|$\rm {H^+ + e^- \rightarrow H}$| + hν | |$k_6=3.50 \times 10^{-12} (\frac{T}{300})^{-0.8}$| |
|$\rm {H_3^+ + O \rightarrow H_2O^+ + H}$| | |$k_{12a}=3.42 \times 10^{-10} (\frac{T}{300})^{-0.2} \rm {xO}$| |
|$\rm {H_3^+ + O \rightarrow OH^+ + H_2}$| | |$k_{12b}=7.98 \times 10^{-10} (\frac{T}{300})^{-0.2} \rm {xO}$| |
|$\rm {H_3^+ + CO \rightarrow HCO^+ + H_2}$| | |$k_{12c}=1.36 \times 10^{-9} (\frac{T}{300})^{-0.1} \rm {exp}(\frac{3.40}{T}) \rm {xCO}$| |
|$\rm {H_3^+ + CO \rightarrow HOC^+ + H_2}$| | |$k_{12d}=8.49 \times 10^{-10} (\frac{T}{300})^{0.1} \rm {exp}(\frac{-5.20}{T}) \rm {xCO}$| |
|$\rm {H_3^+ + O_2 \rightarrow O_2H^+ + H_2}$| | |$k_{12e}=9.30 \times 10^{-10} \rm {exp}(\frac{-100.00}{T}) \rm {xO_2}$| |
|$\rm {H_3^+ + Mg \rightarrow Mg^+ + H + H_2}$| | |$k_{13}=1.0 \times 10^{-9} \rm {xM}$| |
|$\rm {HCO^+ + Mg \rightarrow Mg^+ + HCO}$| | |$k_{23}=2.9 \times 10^{-9} \rm {xM}$| |
|$\rm {He^+ + O_2 \rightarrow O^+ + O + He}$| | |$k_{42}=1.1 \times 10^{-9} \rm {xO_2}$| |
|$\rm {He^+ + CO \rightarrow C^+ + O + He}$| | |$k_{45}=1.6 \times 10^{-9} \rm {xCO}$| |
|$\rm {He^+ + H_2 \rightarrow H^+ + H + He}$| | |$k_{46}=3.7 \times 10^{-14} \rm {exp}(\frac{-35.0}{T}) \rm {xH_2}$| |
|$\rm {C^+ + H_2 \rightarrow CH_2^+}$| + hν | |$k_{52a}=4.0 \times 10^{-16} \left(\frac{T}{300} \right)^{-0.2} \rm {xH_2}$| |
|$\rm {C^+ + O_2 \rightarrow CO^+ + O}$| | |$k_{52b}=3.42 \times 10^{-10} \rm {xO_2}$| |
|$\rm {C^+ + O_2 \rightarrow CO + O^+}$| | |$k_{52c}=4.54 \times 10^{-10} \rm {xO_2}$| |
|$\rm {C^+ + Mg \rightarrow Mg^+ + C}$| | |$k_{53}=1.1 \times 10^{-9} \rm {xM}$| |
|$\rm {H^+ + O \rightarrow O^+ + H}$| | |$k_{62a}=6.86 \times 10^{-10} (\frac{T}{300})^{0.3} \rm {exp} (\frac{-224.30}{T}) \rm {xO}$| |
|$\rm {H^+ + O_2 \rightarrow O_2^+ + H}$| | |$k_{62b}=2.00 \times 10^{-9} \rm {xO_2}$| |
|$\rm {H^+ + Mg \rightarrow Mg^+ + H}$| | |$k_{63}=1.1 \times 10^{-9} \rm {xM}$| |
|$\rm {He^+ + H_2 \rightarrow H_2^+ + He}$| | |$k_{41}=7.2 \times 10^{-15} \rm {xH_2}$| |
Reaction . | Rate (|$\rm {cm^3\, s^{-1}}$|) . |
---|---|
|$\rm {H_3^+ + e^- \rightarrow H_2 + H}$| | |$k_{1a}=2.34 \times 10^{-8} (\frac{T}{300})^{-0.5}$| |
|$\rm {H_3^+ + e^- \rightarrow H+H+H}$| | |$k_{1b}=4.36 \times 10^{-8} (\frac{T}{300})^{-0.5}$| |
|$\rm {HCO^+ + e^- \rightarrow CO + H}$| | |$k_2=2.4 \times 10^{-7} (\frac{T}{300})^{-0.7}$| |
|$\rm {Mg^+ + e^- \rightarrow Mg}$| + hν | |$k_3=2.78 \times 10^{-12} (\frac{T}{300})^{-0.7}$| |
|$\rm {He^+ + e^- \rightarrow He}$| + hν | |$k_4=5.36 \times 10^{-12} (\frac{T}{300})^{-0.5}$| |
|$\rm {C^+ + e^- \rightarrow C}$| + hν | |$k_5=2.36 \times 10^{-12} (\frac{T}{300})^{-0.3} \rm {exp}(\frac{-17.6}{T})$| |
|$\rm {H^+ + e^- \rightarrow H}$| + hν | |$k_6=3.50 \times 10^{-12} (\frac{T}{300})^{-0.8}$| |
|$\rm {H_3^+ + O \rightarrow H_2O^+ + H}$| | |$k_{12a}=3.42 \times 10^{-10} (\frac{T}{300})^{-0.2} \rm {xO}$| |
|$\rm {H_3^+ + O \rightarrow OH^+ + H_2}$| | |$k_{12b}=7.98 \times 10^{-10} (\frac{T}{300})^{-0.2} \rm {xO}$| |
|$\rm {H_3^+ + CO \rightarrow HCO^+ + H_2}$| | |$k_{12c}=1.36 \times 10^{-9} (\frac{T}{300})^{-0.1} \rm {exp}(\frac{3.40}{T}) \rm {xCO}$| |
|$\rm {H_3^+ + CO \rightarrow HOC^+ + H_2}$| | |$k_{12d}=8.49 \times 10^{-10} (\frac{T}{300})^{0.1} \rm {exp}(\frac{-5.20}{T}) \rm {xCO}$| |
|$\rm {H_3^+ + O_2 \rightarrow O_2H^+ + H_2}$| | |$k_{12e}=9.30 \times 10^{-10} \rm {exp}(\frac{-100.00}{T}) \rm {xO_2}$| |
|$\rm {H_3^+ + Mg \rightarrow Mg^+ + H + H_2}$| | |$k_{13}=1.0 \times 10^{-9} \rm {xM}$| |
|$\rm {HCO^+ + Mg \rightarrow Mg^+ + HCO}$| | |$k_{23}=2.9 \times 10^{-9} \rm {xM}$| |
|$\rm {He^+ + O_2 \rightarrow O^+ + O + He}$| | |$k_{42}=1.1 \times 10^{-9} \rm {xO_2}$| |
|$\rm {He^+ + CO \rightarrow C^+ + O + He}$| | |$k_{45}=1.6 \times 10^{-9} \rm {xCO}$| |
|$\rm {He^+ + H_2 \rightarrow H^+ + H + He}$| | |$k_{46}=3.7 \times 10^{-14} \rm {exp}(\frac{-35.0}{T}) \rm {xH_2}$| |
|$\rm {C^+ + H_2 \rightarrow CH_2^+}$| + hν | |$k_{52a}=4.0 \times 10^{-16} \left(\frac{T}{300} \right)^{-0.2} \rm {xH_2}$| |
|$\rm {C^+ + O_2 \rightarrow CO^+ + O}$| | |$k_{52b}=3.42 \times 10^{-10} \rm {xO_2}$| |
|$\rm {C^+ + O_2 \rightarrow CO + O^+}$| | |$k_{52c}=4.54 \times 10^{-10} \rm {xO_2}$| |
|$\rm {C^+ + Mg \rightarrow Mg^+ + C}$| | |$k_{53}=1.1 \times 10^{-9} \rm {xM}$| |
|$\rm {H^+ + O \rightarrow O^+ + H}$| | |$k_{62a}=6.86 \times 10^{-10} (\frac{T}{300})^{0.3} \rm {exp} (\frac{-224.30}{T}) \rm {xO}$| |
|$\rm {H^+ + O_2 \rightarrow O_2^+ + H}$| | |$k_{62b}=2.00 \times 10^{-9} \rm {xO_2}$| |
|$\rm {H^+ + Mg \rightarrow Mg^+ + H}$| | |$k_{63}=1.1 \times 10^{-9} \rm {xM}$| |
|$\rm {He^+ + H_2 \rightarrow H_2^+ + He}$| | |$k_{41}=7.2 \times 10^{-15} \rm {xH_2}$| |
Reaction . | Rate (|$\rm {cm^3\, s^{-1}}$|) . |
---|---|
|$\rm {H_3^+ + e^- \rightarrow H_2 + H}$| | |$k_{1a}=2.34 \times 10^{-8} (\frac{T}{300})^{-0.5}$| |
|$\rm {H_3^+ + e^- \rightarrow H+H+H}$| | |$k_{1b}=4.36 \times 10^{-8} (\frac{T}{300})^{-0.5}$| |
|$\rm {HCO^+ + e^- \rightarrow CO + H}$| | |$k_2=2.4 \times 10^{-7} (\frac{T}{300})^{-0.7}$| |
|$\rm {Mg^+ + e^- \rightarrow Mg}$| + hν | |$k_3=2.78 \times 10^{-12} (\frac{T}{300})^{-0.7}$| |
|$\rm {He^+ + e^- \rightarrow He}$| + hν | |$k_4=5.36 \times 10^{-12} (\frac{T}{300})^{-0.5}$| |
|$\rm {C^+ + e^- \rightarrow C}$| + hν | |$k_5=2.36 \times 10^{-12} (\frac{T}{300})^{-0.3} \rm {exp}(\frac{-17.6}{T})$| |
|$\rm {H^+ + e^- \rightarrow H}$| + hν | |$k_6=3.50 \times 10^{-12} (\frac{T}{300})^{-0.8}$| |
|$\rm {H_3^+ + O \rightarrow H_2O^+ + H}$| | |$k_{12a}=3.42 \times 10^{-10} (\frac{T}{300})^{-0.2} \rm {xO}$| |
|$\rm {H_3^+ + O \rightarrow OH^+ + H_2}$| | |$k_{12b}=7.98 \times 10^{-10} (\frac{T}{300})^{-0.2} \rm {xO}$| |
|$\rm {H_3^+ + CO \rightarrow HCO^+ + H_2}$| | |$k_{12c}=1.36 \times 10^{-9} (\frac{T}{300})^{-0.1} \rm {exp}(\frac{3.40}{T}) \rm {xCO}$| |
|$\rm {H_3^+ + CO \rightarrow HOC^+ + H_2}$| | |$k_{12d}=8.49 \times 10^{-10} (\frac{T}{300})^{0.1} \rm {exp}(\frac{-5.20}{T}) \rm {xCO}$| |
|$\rm {H_3^+ + O_2 \rightarrow O_2H^+ + H_2}$| | |$k_{12e}=9.30 \times 10^{-10} \rm {exp}(\frac{-100.00}{T}) \rm {xO_2}$| |
|$\rm {H_3^+ + Mg \rightarrow Mg^+ + H + H_2}$| | |$k_{13}=1.0 \times 10^{-9} \rm {xM}$| |
|$\rm {HCO^+ + Mg \rightarrow Mg^+ + HCO}$| | |$k_{23}=2.9 \times 10^{-9} \rm {xM}$| |
|$\rm {He^+ + O_2 \rightarrow O^+ + O + He}$| | |$k_{42}=1.1 \times 10^{-9} \rm {xO_2}$| |
|$\rm {He^+ + CO \rightarrow C^+ + O + He}$| | |$k_{45}=1.6 \times 10^{-9} \rm {xCO}$| |
|$\rm {He^+ + H_2 \rightarrow H^+ + H + He}$| | |$k_{46}=3.7 \times 10^{-14} \rm {exp}(\frac{-35.0}{T}) \rm {xH_2}$| |
|$\rm {C^+ + H_2 \rightarrow CH_2^+}$| + hν | |$k_{52a}=4.0 \times 10^{-16} \left(\frac{T}{300} \right)^{-0.2} \rm {xH_2}$| |
|$\rm {C^+ + O_2 \rightarrow CO^+ + O}$| | |$k_{52b}=3.42 \times 10^{-10} \rm {xO_2}$| |
|$\rm {C^+ + O_2 \rightarrow CO + O^+}$| | |$k_{52c}=4.54 \times 10^{-10} \rm {xO_2}$| |
|$\rm {C^+ + Mg \rightarrow Mg^+ + C}$| | |$k_{53}=1.1 \times 10^{-9} \rm {xM}$| |
|$\rm {H^+ + O \rightarrow O^+ + H}$| | |$k_{62a}=6.86 \times 10^{-10} (\frac{T}{300})^{0.3} \rm {exp} (\frac{-224.30}{T}) \rm {xO}$| |
|$\rm {H^+ + O_2 \rightarrow O_2^+ + H}$| | |$k_{62b}=2.00 \times 10^{-9} \rm {xO_2}$| |
|$\rm {H^+ + Mg \rightarrow Mg^+ + H}$| | |$k_{63}=1.1 \times 10^{-9} \rm {xM}$| |
|$\rm {He^+ + H_2 \rightarrow H_2^+ + He}$| | |$k_{41}=7.2 \times 10^{-15} \rm {xH_2}$| |
Reaction . | Rate (|$\rm {cm^3\, s^{-1}}$|) . |
---|---|
|$\rm {H_3^+ + e^- \rightarrow H_2 + H}$| | |$k_{1a}=2.34 \times 10^{-8} (\frac{T}{300})^{-0.5}$| |
|$\rm {H_3^+ + e^- \rightarrow H+H+H}$| | |$k_{1b}=4.36 \times 10^{-8} (\frac{T}{300})^{-0.5}$| |
|$\rm {HCO^+ + e^- \rightarrow CO + H}$| | |$k_2=2.4 \times 10^{-7} (\frac{T}{300})^{-0.7}$| |
|$\rm {Mg^+ + e^- \rightarrow Mg}$| + hν | |$k_3=2.78 \times 10^{-12} (\frac{T}{300})^{-0.7}$| |
|$\rm {He^+ + e^- \rightarrow He}$| + hν | |$k_4=5.36 \times 10^{-12} (\frac{T}{300})^{-0.5}$| |
|$\rm {C^+ + e^- \rightarrow C}$| + hν | |$k_5=2.36 \times 10^{-12} (\frac{T}{300})^{-0.3} \rm {exp}(\frac{-17.6}{T})$| |
|$\rm {H^+ + e^- \rightarrow H}$| + hν | |$k_6=3.50 \times 10^{-12} (\frac{T}{300})^{-0.8}$| |
|$\rm {H_3^+ + O \rightarrow H_2O^+ + H}$| | |$k_{12a}=3.42 \times 10^{-10} (\frac{T}{300})^{-0.2} \rm {xO}$| |
|$\rm {H_3^+ + O \rightarrow OH^+ + H_2}$| | |$k_{12b}=7.98 \times 10^{-10} (\frac{T}{300})^{-0.2} \rm {xO}$| |
|$\rm {H_3^+ + CO \rightarrow HCO^+ + H_2}$| | |$k_{12c}=1.36 \times 10^{-9} (\frac{T}{300})^{-0.1} \rm {exp}(\frac{3.40}{T}) \rm {xCO}$| |
|$\rm {H_3^+ + CO \rightarrow HOC^+ + H_2}$| | |$k_{12d}=8.49 \times 10^{-10} (\frac{T}{300})^{0.1} \rm {exp}(\frac{-5.20}{T}) \rm {xCO}$| |
|$\rm {H_3^+ + O_2 \rightarrow O_2H^+ + H_2}$| | |$k_{12e}=9.30 \times 10^{-10} \rm {exp}(\frac{-100.00}{T}) \rm {xO_2}$| |
|$\rm {H_3^+ + Mg \rightarrow Mg^+ + H + H_2}$| | |$k_{13}=1.0 \times 10^{-9} \rm {xM}$| |
|$\rm {HCO^+ + Mg \rightarrow Mg^+ + HCO}$| | |$k_{23}=2.9 \times 10^{-9} \rm {xM}$| |
|$\rm {He^+ + O_2 \rightarrow O^+ + O + He}$| | |$k_{42}=1.1 \times 10^{-9} \rm {xO_2}$| |
|$\rm {He^+ + CO \rightarrow C^+ + O + He}$| | |$k_{45}=1.6 \times 10^{-9} \rm {xCO}$| |
|$\rm {He^+ + H_2 \rightarrow H^+ + H + He}$| | |$k_{46}=3.7 \times 10^{-14} \rm {exp}(\frac{-35.0}{T}) \rm {xH_2}$| |
|$\rm {C^+ + H_2 \rightarrow CH_2^+}$| + hν | |$k_{52a}=4.0 \times 10^{-16} \left(\frac{T}{300} \right)^{-0.2} \rm {xH_2}$| |
|$\rm {C^+ + O_2 \rightarrow CO^+ + O}$| | |$k_{52b}=3.42 \times 10^{-10} \rm {xO_2}$| |
|$\rm {C^+ + O_2 \rightarrow CO + O^+}$| | |$k_{52c}=4.54 \times 10^{-10} \rm {xO_2}$| |
|$\rm {C^+ + Mg \rightarrow Mg^+ + C}$| | |$k_{53}=1.1 \times 10^{-9} \rm {xM}$| |
|$\rm {H^+ + O \rightarrow O^+ + H}$| | |$k_{62a}=6.86 \times 10^{-10} (\frac{T}{300})^{0.3} \rm {exp} (\frac{-224.30}{T}) \rm {xO}$| |
|$\rm {H^+ + O_2 \rightarrow O_2^+ + H}$| | |$k_{62b}=2.00 \times 10^{-9} \rm {xO_2}$| |
|$\rm {H^+ + Mg \rightarrow Mg^+ + H}$| | |$k_{63}=1.1 \times 10^{-9} \rm {xM}$| |
|$\rm {He^+ + H_2 \rightarrow H_2^+ + He}$| | |$k_{41}=7.2 \times 10^{-15} \rm {xH_2}$| |
APPENDIX B: DUST REACTIONS
In this appendix, we address collisions between dust grains and charged particles and the absorption of charged particles on to the surfaces of dust grains. Three types of dust grains are considered: positively charged, negatively charged, and neutral. The reactions of these grains with ions and electrons are also considered, such that six reactions are required, as described below. According to Draine & Sutin (1987), the reaction rates can be summarized as itemized below.
- The collisional rate between charged grains and ions (i = 1–6), written as(B1)\begin{eqnarray*} k_{id} (s,z)= \left\lbrace \begin{array}{l}\sqrt{\frac{8 k_B T}{\pi m_i}} \sigma _s \ \rm {exp} \left(-\frac{{\it z}}{(1+|{\it z}|^{-1/2})\tau _s} \right) \ \left\lbrace 1+ \left(\frac{1}{4\tau _s+3{\it z}} \right)^{1/2} \right\rbrace ^2 \qquad ({\it z} \ \rm {\gt 0}) \\ \sqrt{\frac{8 k_B T}{\pi m_i}} \sigma _s \ \left(1-\frac{z}{\tau _s} \right) \ \left\lbrace 1+ \left(\frac{2}{\tau _s-2z} \right)^{1/2} \right\rbrace \qquad (z\lt 0). \end{array} \right. \end{eqnarray*}
- The collisional rate between charged grains and electrons (i = 0), written as(B2)\begin{eqnarray*} k_{id} (s,z)= \left\lbrace \begin{array}{l}\sqrt{\frac{8 k_B T}{\pi m_e}} \sigma _s \ \left(1+\frac{z}{\tau _s} \right) \left\lbrace 1+\left(\frac{2}{\tau _s+2z} \right)^{1/2} \right\rbrace \qquad (z\gt 0) \\ \sqrt{\frac{8 k_B T}{\pi m_e}} \sigma _s \ \rm {exp} \left(\frac{{\it z}}{(1+|{\it z}|^{-1/2})\tau _s} \right) \ \left\lbrace 1+ \left(\frac{1}{4\tau _s-3{\it z}} \right)^{1/2} \right\rbrace ^2 \qquad ({\it z} \ \rm {\lt 0}). \end{array} \right. \end{eqnarray*}
- The collisional rate between neutral grains, electrons, and ions (i = 0–6), written as(B3)\begin{eqnarray*} k_{nd} (s,0) =\sqrt{\frac{8 k_B T}{\pi m_e}} \sigma _s \left\lbrace 1+ \left(\frac{\pi }{2 \tau _s} \right)^{1/2} \right\rbrace . \end{eqnarray*}
APPENDIX C: REACTION EQUATIONS
APPENDIX D: EQUILIBRIUM TIME-SCALE VERSUS FREEFALL TIME-SCALE
In this appendix, we compare the elapsed time required to obtain an equilibrium state with the freefall time-scale at a given density. Fig. D1 shows that chemical abundances of charged species considered in this study reach an equilibrium state within the freefall time-scale.

Chemical abundances of charged species for different gas number density |$10^4, 10^8, 10^{11}, 10^{14}\, \rm {cm^{-3}}$| as a function of ζt (|$\zeta = 10^{-17} \rm {s^{-1}}$|). The freefall time-scale is given by |$t_{\rm ff} = \sqrt{\frac{3 \pi }{32 G \rho }}$|.
In all density, the equilibrium is achieved before the freefall time. Thus, we confirm that the elapsed time necessary for reaching an equilibrium state is much shorter than the freefall time-scale over the density range of |$10^4\, {\rm cm}^{-3} \lt n_{\rm H} \lt 10^{14}\, {\rm cm}^{-3}$|. The validity of the chemical equilibrium is also seen in fig. 13 of Marchand et al. (2016).