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Yosuke Hosoya, Hiroki Yoshikawa, Arata Tsukamoto, Kosuke Sugawa, Joe Otsuki, Alterations in magnetic properties of crystals of trinuclear copper complexes: isolated entities versus one-dimensional chains, Chemistry Letters, Volume 53, Issue 2, February 2024, upad033, https://doi.org/10.1093/chemle/upad033
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Abstract
We obtained two types of crystals of a complex under different crystallization conditions, each exhibiting distinct molecular arrangements and magnetic interactions: one type consists of isolated complexes, while the other forms one-dimensional chains without extra bridging ligands. This approach provides a new avenue for tuning the magnetic properties of metal-complex-based materials.

The same trinuclear copper complex crystalizes in two different arrangements: one with isolated complexes and the other forming one-dimensional chains. This approach provides a new avenue for tuning the magnetic properties of metal-complex-based materials.