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Tomohiro Higashino, Rikiya Iizumi, Hiroshi Imahori, Rational Synthesis of Benzoheterole-fused Porphyrins and π-System Switching by Central Metal Ion, Chemistry Letters, Volume 51, Issue 9, September 2022, Pages 932–935, https://doi.org/10.1246/cl.220277
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Abstract
We developed a rational synthetic approach for benzoheterole-fused porphyrins and demonstrated the synthesis of benzothiophene- and indole-fused porphyrins using the approach. The fused porphyrins exhibited red-shifted absorption and fluorescence due to the effective π-expansion through heterole-fused structures. In addition, the π-circuit of indole-fused porphyrin can be switched by a central metal ion.
© 2022 The Chemical Society of Japan
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