Abstract

Binuclear cobalt(II) complexes, [Co2(bpmp) (CH3COO)2]ClO4 and [Co2(bpmp) (CH3COO)] (ClO4)2 with 2,6-bis[bis(2-pyridylmethyl)aminomethyl]-4-methylphenol (Hbpmp), were prepared. The complexes showed the reversible oxygenation in various solvents. Two to one (CO/O2) peroxo bridged complex, [Co2(bpmp)(CH3COO)O2](ClO4)2·2H2O, was isolated. The oxygen adduct was fairly stable towards further reactions.

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