Figure 7.
Speculated hydrogen bonds between T-vinyl 2 and a uracil base. A bridging water molecule was assumed in 19. A close proximity between 6-NH2 of 5′-A is shown schematically in 20. The cross-link formed with the N3 of the opposite U likely by the reaction with its enol or enolate form as shown in 21.

Speculated hydrogen bonds between T-vinyl 2 and a uracil base. A bridging water molecule was assumed in 19. A close proximity between 6-NH2 of 5′-A is shown schematically in 20. The cross-link formed with the N3 of the opposite U likely by the reaction with its enol or enolate form as shown in 21.

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