Figure 6.
Synthesis of negatively curved molecular carbons. (a) Several negatively curved PAHs containing seven- or eight-membered rings. Adapted with permission from refs [30,137,139–142]. Copyright 2019 John Wiley and Sons; copyright 2013 Springer Nature; copyright 2023 Elsevier; copyright 2023 American Chemical Society; copyright 2019 John Wiley and Sons; copyright 2022 American Chemical Society. (b, c) Typical synthetic routes for preparing PAHs containing [8]circulene units by (b) in-out and (c) out-in cyclization. Adapted with permission from refs [29,138]. Copyright 2019 American Chemical Society; copyright 2017 John Wiley and Sons.