Figure 7.
(a) Crystal structure of MnNCN. Mn ions are coordinated to form MnN6 octahedra and carbon bridges the gaps to connect N atoms on alternating layers. (b) The coordination of metal centers and energy levels of MnNCN and MnO. MnNCN is more covalently bound than MnO because C and N are both less electronegative than O [181].

(a) Crystal structure of MnNCN. Mn ions are coordinated to form MnN6 octahedra and carbon bridges the gaps to connect N atoms on alternating layers. (b) The coordination of metal centers and energy levels of MnNCN and MnO. MnNCN is more covalently bound than MnO because C and N are both less electronegative than O [181].

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