Table 1. Open in new tab Overview of the...

No.	Experiments	T_sample	Ratio	Flux_(CO+CH3OH)	Flux_H	Flux_UV	Time	COM composition fraction
1	CO + CH₃OH + H	14	4:1	1.2E13	6.0E12	–	3600	0.0	0.2	0.8
2	CO + CH₃OH + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
3	CO + CH₃OH + H + hν	14	4:1	1.2E13	6.0E12	4.0E12	3600	0.2	0.3	0.5


No.	Control experiments	T_sample	Ratio	Flux_(CO+CH3OH)	Flux_H	Flux_UV	Time	COM composition fraction
		(K)	(CO:CH₃OH)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(s)	MF HC(O)OCH₃	GA HC(O)CH₂OH	EG H₂C(OH)CH₂OH
1.1	CO + CH₃OH + H₂	14	4:1	1.2E13	–	–	3600	–	–	–
1.2	CO + CH₃OH + H	14	4:1	2.0E12	1.0E12	–	21600	<0.05	0.4	0.6
1.3	CO + CH₃OH + H	14	4:1	2.0E12	6.0E12	–	21600	<0.05	0.6	0.4
3.1	CO + CH₃OH + H₂	14	4:1	1.2E13	–	–	3600	–	–	–
3.2	CO + CH₃OH + H₂(100%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
3.3	CO + CH₃OH + H₂(70%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
4.1	CO + CH₃OH + Ar(100%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.20	0.25	0.55
4.2	CO + CH₃OH + Ar(70%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
4.3	CO + CH₃OH + Ar(30%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5

No.

Experiments

T_sample

Ratio

Flux_(CO+CH3OH)

Flux_H

Flux_UV

Time

COM composition fraction

(K)

(CO:CH₃OH)

(cm⁻²s⁻¹)

(s)

MF HC(O)OCH₃

GA HC(O)CH₂OH

EG H₂C(OH)CH₂OH

CO + CH₃OH + H

4:1

1.2E13

6.0E12

–

3600

0.0

0.2

0.8

CO + CH₃OH + hν

4:1

1.2E13

–

4.0E12

3600

0.2

0.3

0.5

CO + CH₃OH + H + hν

4:1

1.2E13

6.0E12

4.0E12

3600

0.2

0.3

0.5

No.

Control experiments

T_sample

Ratio

Flux_(CO+CH3OH)

Flux_H

Flux_UV

Time

COM composition fraction

(K)

(CO:CH₃OH)

(cm⁻²s⁻¹)

(s)

MF HC(O)OCH₃

GA HC(O)CH₂OH

EG H₂C(OH)CH₂OH

1.1

CO + CH₃OH + H₂

4:1

1.2E13

–

3600

–

1.2

CO + CH₃OH + H

4:1

2.0E12

1.0E12

–

21600

<0.05

0.4

0.6

1.3

CO + CH₃OH + H

4:1

2.0E12

6.0E12

–

21600

<0.05

0.6

0.4

3.1

CO + CH₃OH + H₂

4:1

1.2E13

–

3600

–

3.2

CO + CH₃OH + H₂(100%) + hν

4:1

1.2E13

–

4.0E12

3600

0.2

0.3

0.5

3.3

CO + CH₃OH + H₂(70%) + hν

4:1

1.2E13

–

4.0E12

3600

0.2

0.3

0.5

4.1

CO + CH₃OH + Ar(100%) + hν

4:1

1.2E13

–

4.0E12

3600

0.20

0.25

0.55

4.2

CO + CH₃OH + Ar(70%) + hν

4:1

1.2E13

–

4.0E12

3600

0.2

0.3

0.5

4.3

CO + CH₃OH + Ar(30%) + hν

4:1

1.2E13

–

4.0E12

3600

0.2

0.3

0.5

No.	Experiments	T_sample	Ratio	Flux_(CO+CH3OH)	Flux_H	Flux_UV	Time	COM composition fraction
1	CO + CH₃OH + H	14	4:1	1.2E13	6.0E12	–	3600	0.0	0.2	0.8
2	CO + CH₃OH + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
3	CO + CH₃OH + H + hν	14	4:1	1.2E13	6.0E12	4.0E12	3600	0.2	0.3	0.5


No.	Control experiments	T_sample	Ratio	Flux_(CO+CH3OH)	Flux_H	Flux_UV	Time	COM composition fraction
		(K)	(CO:CH₃OH)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(s)	MF HC(O)OCH₃	GA HC(O)CH₂OH	EG H₂C(OH)CH₂OH
1.1	CO + CH₃OH + H₂	14	4:1	1.2E13	–	–	3600	–	–	–
1.2	CO + CH₃OH + H	14	4:1	2.0E12	1.0E12	–	21600	<0.05	0.4	0.6
1.3	CO + CH₃OH + H	14	4:1	2.0E12	6.0E12	–	21600	<0.05	0.6	0.4
3.1	CO + CH₃OH + H₂	14	4:1	1.2E13	–	–	3600	–	–	–
3.2	CO + CH₃OH + H₂(100%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
3.3	CO + CH₃OH + H₂(70%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
4.1	CO + CH₃OH + Ar(100%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.20	0.25	0.55
4.2	CO + CH₃OH + Ar(70%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
4.3	CO + CH₃OH + Ar(30%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5

Table 1.

Open in new tab

Overview of the performed experiments.

No.	Experiments	T_sample	Ratio	Flux_(CO+CH3OH)	Flux_H	Flux_UV	Time	COM composition fraction
		(K)	(CO:CH₃OH)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(s)	MF HC(O)OCH₃	GA HC(O)CH₂OH	EG H₂C(OH)CH₂OH
1	CO + CH₃OH + H	14	4:1	1.2E13	6.0E12	–	3600	0.0	0.2	0.8
2	CO + CH₃OH + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
3	CO + CH₃OH + H + hν	14	4:1	1.2E13	6.0E12	4.0E12	3600	0.2	0.3	0.5


No.	Control experiments	T_sample	Ratio	Flux_(CO+CH3OH)	Flux_H	Flux_UV	Time	COM composition fraction
		(K)	(CO:CH₃OH)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(s)	MF HC(O)OCH₃	GA HC(O)CH₂OH	EG H₂C(OH)CH₂OH
1.1	CO + CH₃OH + H₂	14	4:1	1.2E13	–	–	3600	–	–	–
1.2	CO + CH₃OH + H	14	4:1	2.0E12	1.0E12	–	21600	<0.05	0.4	0.6
1.3	CO + CH₃OH + H	14	4:1	2.0E12	6.0E12	–	21600	<0.05	0.6	0.4
3.1	CO + CH₃OH + H₂	14	4:1	1.2E13	–	–	3600	–	–	–
3.2	CO + CH₃OH + H₂(100%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
3.3	CO + CH₃OH + H₂(70%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
4.1	CO + CH₃OH + Ar(100%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.20	0.25	0.55
4.2	CO + CH₃OH + Ar(70%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
4.3	CO + CH₃OH + Ar(30%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5

No.	Experiments	T_sample	Ratio	Flux_(CO+CH3OH)	Flux_H	Flux_UV	Time	COM composition fraction
		(K)	(CO:CH₃OH)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(s)	MF HC(O)OCH₃	GA HC(O)CH₂OH	EG H₂C(OH)CH₂OH
1	CO + CH₃OH + H	14	4:1	1.2E13	6.0E12	–	3600	0.0	0.2	0.8
2	CO + CH₃OH + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
3	CO + CH₃OH + H + hν	14	4:1	1.2E13	6.0E12	4.0E12	3600	0.2	0.3	0.5


No.	Control experiments	T_sample	Ratio	Flux_(CO+CH3OH)	Flux_H	Flux_UV	Time	COM composition fraction
		(K)	(CO:CH₃OH)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(cm⁻²s⁻¹)	(s)	MF HC(O)OCH₃	GA HC(O)CH₂OH	EG H₂C(OH)CH₂OH
1.1	CO + CH₃OH + H₂	14	4:1	1.2E13	–	–	3600	–	–	–
1.2	CO + CH₃OH + H	14	4:1	2.0E12	1.0E12	–	21600	<0.05	0.4	0.6
1.3	CO + CH₃OH + H	14	4:1	2.0E12	6.0E12	–	21600	<0.05	0.6	0.4
3.1	CO + CH₃OH + H₂	14	4:1	1.2E13	–	–	3600	–	–	–
3.2	CO + CH₃OH + H₂(100%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
3.3	CO + CH₃OH + H₂(70%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
4.1	CO + CH₃OH + Ar(100%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.20	0.25	0.55
4.2	CO + CH₃OH + Ar(70%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5
4.3	CO + CH₃OH + Ar(30%) + hν	14	4:1	1.2E13	–	4.0E12	3600	0.2	0.3	0.5

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