| Entry . | Conc. (M) . | Equiv . | Z/W (mL/min) . | T (°C) . | HPLC-UV Yield of 3 (%)a . | ||
|---|---|---|---|---|---|---|---|
| V1 . | V2 . | X . | Y . | ||||
| 1 | 0.1 | 0.25 | 1.0 | 1.5 | 1.67 (Z2.0/W1.2) | 20 | 90 ± 1 |
| 2 | 0.1 | 0.1 | 1.0 | 2.2 | 0.45 (Z1.0/W2.2) | 30 | 94 ± 1 |
| 3 | 0.1 | 0.37 | 1.0 | 2.2 | 1.67 (Z2.0/W1.2) | 20 | 86 ± 1 |
| 4 | 0.1 | 0.37 | 1.0 | 2.2 | 1.67 (Z2.0/W1.2) | 30 | 89.5 ± 0.5 |
| 5 | 0.13 | 0.28 | 1.0 | 2.2 | 1.00 (Z1.6/W1.6) | 30 | 90 ± 1 |
| 6 | 0.17 | 0.22 | 1.0 | 2.2 | 0.60 (Z1.2/W2.0) | 30 | 88 ± 2 |
| Entry . | Conc. (M) . | Equiv . | Z/W (mL/min) . | T (°C) . | HPLC-UV Yield of 3 (%)a . | ||
|---|---|---|---|---|---|---|---|
| V1 . | V2 . | X . | Y . | ||||
| 1 | 0.1 | 0.25 | 1.0 | 1.5 | 1.67 (Z2.0/W1.2) | 20 | 90 ± 1 |
| 2 | 0.1 | 0.1 | 1.0 | 2.2 | 0.45 (Z1.0/W2.2) | 30 | 94 ± 1 |
| 3 | 0.1 | 0.37 | 1.0 | 2.2 | 1.67 (Z2.0/W1.2) | 20 | 86 ± 1 |
| 4 | 0.1 | 0.37 | 1.0 | 2.2 | 1.67 (Z2.0/W1.2) | 30 | 89.5 ± 0.5 |
| 5 | 0.13 | 0.28 | 1.0 | 2.2 | 1.00 (Z1.6/W1.6) | 30 | 90 ± 1 |
| 6 | 0.17 | 0.22 | 1.0 | 2.2 | 0.60 (Z1.2/W2.0) | 30 | 88 ± 2 |
aThree independent experiments were carried out.
| Entry . | Conc. (M) . | Equiv . | Z/W (mL/min) . | T (°C) . | HPLC-UV Yield of 3 (%)a . | ||
|---|---|---|---|---|---|---|---|
| V1 . | V2 . | X . | Y . | ||||
| 1 | 0.1 | 0.25 | 1.0 | 1.5 | 1.67 (Z2.0/W1.2) | 20 | 90 ± 1 |
| 2 | 0.1 | 0.1 | 1.0 | 2.2 | 0.45 (Z1.0/W2.2) | 30 | 94 ± 1 |
| 3 | 0.1 | 0.37 | 1.0 | 2.2 | 1.67 (Z2.0/W1.2) | 20 | 86 ± 1 |
| 4 | 0.1 | 0.37 | 1.0 | 2.2 | 1.67 (Z2.0/W1.2) | 30 | 89.5 ± 0.5 |
| 5 | 0.13 | 0.28 | 1.0 | 2.2 | 1.00 (Z1.6/W1.6) | 30 | 90 ± 1 |
| 6 | 0.17 | 0.22 | 1.0 | 2.2 | 0.60 (Z1.2/W2.0) | 30 | 88 ± 2 |
| Entry . | Conc. (M) . | Equiv . | Z/W (mL/min) . | T (°C) . | HPLC-UV Yield of 3 (%)a . | ||
|---|---|---|---|---|---|---|---|
| V1 . | V2 . | X . | Y . | ||||
| 1 | 0.1 | 0.25 | 1.0 | 1.5 | 1.67 (Z2.0/W1.2) | 20 | 90 ± 1 |
| 2 | 0.1 | 0.1 | 1.0 | 2.2 | 0.45 (Z1.0/W2.2) | 30 | 94 ± 1 |
| 3 | 0.1 | 0.37 | 1.0 | 2.2 | 1.67 (Z2.0/W1.2) | 20 | 86 ± 1 |
| 4 | 0.1 | 0.37 | 1.0 | 2.2 | 1.67 (Z2.0/W1.2) | 30 | 89.5 ± 0.5 |
| 5 | 0.13 | 0.28 | 1.0 | 2.2 | 1.00 (Z1.6/W1.6) | 30 | 90 ± 1 |
| 6 | 0.17 | 0.22 | 1.0 | 2.2 | 0.60 (Z1.2/W2.0) | 30 | 88 ± 2 |
aThree independent experiments were carried out.
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