| Sample . | TKL02-2 . | . | TKL18-4 . | . | MS02-3 . | |||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Mineral . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . |
| Texture | Pl-1 | Pl-2 | Incl. | Pl-1 | Pl-2 | Incl. | Pl-1 | Pl-2 | Pl-s1 | Pl-s2 | Incl. | |||||||
| Domain | core | rim | core | rim | core | rim | core | rim | core | mantle | rim | core | rim | |||||
| SiO2 (wt%) | 58.92 | 55.70 | 54.25 | 53.75 | 59.16 | 59.22 | 54.25 | 54.98 | 54.82 | 57.06 | 57.24 | 53.69 | 50.99 | 55.49 | 53.24 | 48.57 | 47.86 | 56.67 |
| TiO2 | 0.01 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.04 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| Al2O3 | 25.34 | 27.59 | 28.56 | 28.83 | 25.33 | 25.16 | 28.47 | 28.12 | 28.06 | 26.16 | 26.54 | 28.69 | 29.96 | 27.85 | 28.86 | 31.89 | 33.10 | 26.72 |
| Cr2O3 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.05 | 0.00 | 0.00 | 0.04 | 0.01 | 0.03 | 0.00 | 0.01 | 0.03 | 0.00 | 0.02 | 0.00 |
| FeO | 0.12 | 0.15 | 0.16 | 0.15 | 0.11 | 0.16 | 0.30 | 0.13 | 0.31 | 0.58 | 0.08 | 0.37 | 0.54 | 0.14 | 0.25 | 0.71 | 0.31 | 0.17 |
| MnO | 0.02 | 0.03 | 0.00 | 0.05 | 0.00 | 0.01 | 0.00 | 0.00 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.01 | 0.01 | 0.00 | 0.01 | 0.00 |
| MgO | 0.00 | 0.02 | 0.01 | 0.01 | 0.00 | 0.01 | 0.01 | 0.01 | 0.00 | 0.03 | 0.02 | 0.01 | 0.14 | 0.00 | 0.01 | 0.00 | 0.01 | 0.03 |
| CaO | 7.39 | 10.85 | 11.03 | 12.17 | 7.41 | 6.99 | 10.67 | 10.51 | 11.48 | 8.85 | 9.24 | 12.35 | 14.10 | 11.28 | 12.35 | 15.84 | 16.78 | 10.08 |
| Na2O | 6.75 | 4.90 | 4.83 | 4.21 | 6.64 | 7.17 | 5.32 | 5.44 | 4.87 | 6.01 | 5.99 | 4.39 | 3.42 | 4.92 | 4.27 | 2.12 | 1.48 | 5.39 |
| K2O | 0.57 | 0.37 | 0.39 | 0.38 | 0.56 | 0.50 | 0.25 | 0.19 | 0.20 | 0.42 | 0.31 | 0.14 | 0.14 | 0.21 | 0.18 | 0.04 | 0.03 | 0.40 |
| Total | 99.13 | 99.63 | 99.28 | 99.57 | 99.22 | 99.25 | 99.35 | 99.39 | 99.77 | 99.29 | 99.44 | 99.74 | 99.35 | 99.93 | 99.23 | 99.25 | 99.63 | 99.48 |
| O cations | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 |
| Si (p.f.u.) | 2.653 | 2.517 | 2.466 | 2.442 | 2.659 | 2.663 | 2.465 | 2.492 | 2.481 | 2.581 | 2.580 | 2.437 | 2.340 | 2.502 | 2.429 | 2.240 | 2.199 | 2.559 |
| Ti | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Al | 1.345 | 1.470 | 1.530 | 1.544 | 1.342 | 1.334 | 1.525 | 1.502 | 1.497 | 1.395 | 1.411 | 1.535 | 1.621 | 1.481 | 1.552 | 1.734 | 1.793 | 1.423 |
| Cr | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.002 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 |
| Fe3+ | 0.005 | 0.006 | 0.006 | 0.006 | 0.004 | 0.006 | 0.011 | 0.005 | 0.012 | 0.022 | 0.003 | 0.014 | 0.021 | 0.005 | 0.010 | 0.027 | 0.012 | 0.006 |
| Fe2+ | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Mn | 0.001 | 0.001 | 0.000 | 0.002 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Mg | 0.000 | 0.001 | 0.001 | 0.001 | 0.000 | 0.001 | 0.001 | 0.001 | 0.000 | 0.002 | 0.001 | 0.001 | 0.010 | 0.000 | 0.001 | 0.000 | 0.001 | 0.002 |
| Ca | 0.357 | 0.525 | 0.537 | 0.592 | 0.357 | 0.337 | 0.520 | 0.510 | 0.557 | 0.429 | 0.446 | 0.601 | 0.693 | 0.545 | 0.604 | 0.783 | 0.826 | 0.488 |
| Na | 0.589 | 0.429 | 0.426 | 0.371 | 0.579 | 0.625 | 0.469 | 0.478 | 0.427 | 0.527 | 0.524 | 0.386 | 0.304 | 0.430 | 0.378 | 0.190 | 0.132 | 0.472 |
| K | 0.033 | 0.021 | 0.023 | 0.022 | 0.032 | 0.029 | 0.014 | 0.011 | 0.012 | 0.025 | 0.018 | 0.008 | 0.008 | 0.012 | 0.010 | 0.002 | 0.002 | 0.023 |
| XAn | 0.36 | 0.54 | 0.54 | 0.60 | 0.37 | 0.34 | 0.52 | 0.51 | 0.56 | 0.44 | 0.45 | 0.60 | 0.69 | 0.55 | 0.61 | 0.80 | 0.86 | 0.50 |
| SiO2 (wt%) | 57.07 | 55.59 | 51.34 | 53.70 | 53.26 | 47.57 | 48.71 | 56.29 | 53.98 | 54.33 | 49.63 | 53.41 | 48.41 | 46.20 | 46.54 | 54.55 | ||
| TiO2 | 0.00 | 0.00 | 0.00 | 0.01 | 0.04 | 0.00 | 0.00 | 0.01 | 0.00 | 0.01 | 0.00 | 0.01 | 0.01 | 0.00 | 0.00 | 0.04 | ||
| Al2O3 | 26.70 | 27.78 | 30.62 | 27.89 | 29.23 | 32.23 | 32.34 | 26.89 | 29.02 | 29.00 | 32.24 | 29.37 | 32.94 | 34.42 | 34.22 | 28.98 | ||
| Cr2O3 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.00 | 0.03 | 0.03 | 0.02 | 0.03 | 0.02 | 0.00 | 0.00 | 0.01 | 0.01 | 0.02 | ||
| FeO | 0.13 | 0.12 | 0.33 | 0.15 | 0.00 | 0.80 | 0.30 | 0.37 | 0.12 | 0.16 | 0.17 | 0.12 | 0.17 | 0.35 | 0.30 | 0.09 | ||
| MnO | 0.00 | 0.03 | 0.00 | 0.01 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 | 0.02 | 0.01 | 0.02 | 0.00 | 0.02 | 0.04 | ||
| MgO | 0.02 | 0.00 | 0.01 | 0.02 | 0.14 | 0.55 | 0.01 | 0.01 | 0.02 | 0.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 | ||
| CaO | 9.55 | 11.07 | 14.57 | 10.84 | 12.13 | 15.19 | 16.12 | 9.56 | 10.75 | 10.88 | 14.82 | 11.19 | 15.13 | 17.32 | 17.19 | 10.92 | ||
| Na2O | 5.64 | 4.61 | 2.97 | 5.00 | 4.38 | 2.43 | 1.96 | 5.71 | 5.06 | 4.66 | 2.85 | 4.56 | 2.58 | 1.39 | 1.54 | 4.70 | ||
| K2O | 0.40 | 0.30 | 0.10 | 0.34 | 0.27 | 0.13 | 0.08 | 0.44 | 0.43 | 0.38 | 0.16 | 0.33 | 0.11 | 0.04 | 0.06 | 0.34 | ||
| Total | 99.52 | 99.56 | 99.98 | 97.98 | ##### | 98.99 | 99.58 | 99.35 | 99.40 | 99.50 | 99.94 | 99.01 | 99.38 | 99.77 | 99.91 | 99.69 | ||
| O cations | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | ||
| Si (p.f.u.) | 2.572 | 2.512 | 2.336 | 2.474 | 2.410 | 2.204 | 2.236 | 2.548 | 2.451 | 2.460 | 2.265 | 2.434 | 2.225 | 2.128 | 2.140 | 2.465 | ||
| Ti | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Al | 1.419 | 1.480 | 1.643 | 1.515 | 1.559 | 1.760 | 1.750 | 1.435 | 1.553 | 1.548 | 1.735 | 1.578 | 1.785 | 1.870 | 1.856 | 1.544 | ||
| Cr | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Fe3+ | 0.005 | 0.006 | 0.013 | 0.006 | 0.026 | 0.031 | 0.012 | 0.014 | 0.004 | 0.006 | 0.007 | 0.004 | 0.006 | 0.013 | 0.012 | 0.003 | ||
| Fe2+ | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | ||
| Mn | 0.000 | 0.001 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.001 | 0.001 | ||
| Mg | 0.001 | 0.000 | 0.001 | 0.001 | 0.009 | 0.038 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Ca | 0.461 | 0.536 | 0.710 | 0.535 | 0.588 | 0.754 | 0.793 | 0.464 | 0.523 | 0.528 | 0.725 | 0.546 | 0.745 | 0.855 | 0.847 | 0.529 | ||
| Na | 0.493 | 0.404 | 0.262 | 0.447 | 0.384 | 0.218 | 0.174 | 0.501 | 0.446 | 0.409 | 0.252 | 0.403 | 0.230 | 0.124 | 0.137 | 0.412 | ||
| K | 0.023 | 0.017 | 0.006 | 0.020 | 0.016 | 0.008 | 0.005 | 0.025 | 0.025 | 0.022 | 0.009 | 0.019 | 0.007 | 0.002 | 0.004 | 0.020 | ||
| XAn | 0.47 | 0.56 | 0.73 | 0.53 | 0.60 | 0.77 | 0.82 | 0.47 | 0.53 | 0.55 | 0.74 | 0.56 | 0.76 | 0.87 | 0.86 | 0.55 | ||
| Sample . | TKL02-2 . | . | TKL18-4 . | . | MS02-3 . | |||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Mineral . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . |
| Texture | Pl-1 | Pl-2 | Incl. | Pl-1 | Pl-2 | Incl. | Pl-1 | Pl-2 | Pl-s1 | Pl-s2 | Incl. | |||||||
| Domain | core | rim | core | rim | core | rim | core | rim | core | mantle | rim | core | rim | |||||
| SiO2 (wt%) | 58.92 | 55.70 | 54.25 | 53.75 | 59.16 | 59.22 | 54.25 | 54.98 | 54.82 | 57.06 | 57.24 | 53.69 | 50.99 | 55.49 | 53.24 | 48.57 | 47.86 | 56.67 |
| TiO2 | 0.01 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.04 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| Al2O3 | 25.34 | 27.59 | 28.56 | 28.83 | 25.33 | 25.16 | 28.47 | 28.12 | 28.06 | 26.16 | 26.54 | 28.69 | 29.96 | 27.85 | 28.86 | 31.89 | 33.10 | 26.72 |
| Cr2O3 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.05 | 0.00 | 0.00 | 0.04 | 0.01 | 0.03 | 0.00 | 0.01 | 0.03 | 0.00 | 0.02 | 0.00 |
| FeO | 0.12 | 0.15 | 0.16 | 0.15 | 0.11 | 0.16 | 0.30 | 0.13 | 0.31 | 0.58 | 0.08 | 0.37 | 0.54 | 0.14 | 0.25 | 0.71 | 0.31 | 0.17 |
| MnO | 0.02 | 0.03 | 0.00 | 0.05 | 0.00 | 0.01 | 0.00 | 0.00 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.01 | 0.01 | 0.00 | 0.01 | 0.00 |
| MgO | 0.00 | 0.02 | 0.01 | 0.01 | 0.00 | 0.01 | 0.01 | 0.01 | 0.00 | 0.03 | 0.02 | 0.01 | 0.14 | 0.00 | 0.01 | 0.00 | 0.01 | 0.03 |
| CaO | 7.39 | 10.85 | 11.03 | 12.17 | 7.41 | 6.99 | 10.67 | 10.51 | 11.48 | 8.85 | 9.24 | 12.35 | 14.10 | 11.28 | 12.35 | 15.84 | 16.78 | 10.08 |
| Na2O | 6.75 | 4.90 | 4.83 | 4.21 | 6.64 | 7.17 | 5.32 | 5.44 | 4.87 | 6.01 | 5.99 | 4.39 | 3.42 | 4.92 | 4.27 | 2.12 | 1.48 | 5.39 |
| K2O | 0.57 | 0.37 | 0.39 | 0.38 | 0.56 | 0.50 | 0.25 | 0.19 | 0.20 | 0.42 | 0.31 | 0.14 | 0.14 | 0.21 | 0.18 | 0.04 | 0.03 | 0.40 |
| Total | 99.13 | 99.63 | 99.28 | 99.57 | 99.22 | 99.25 | 99.35 | 99.39 | 99.77 | 99.29 | 99.44 | 99.74 | 99.35 | 99.93 | 99.23 | 99.25 | 99.63 | 99.48 |
| O cations | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 |
| Si (p.f.u.) | 2.653 | 2.517 | 2.466 | 2.442 | 2.659 | 2.663 | 2.465 | 2.492 | 2.481 | 2.581 | 2.580 | 2.437 | 2.340 | 2.502 | 2.429 | 2.240 | 2.199 | 2.559 |
| Ti | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Al | 1.345 | 1.470 | 1.530 | 1.544 | 1.342 | 1.334 | 1.525 | 1.502 | 1.497 | 1.395 | 1.411 | 1.535 | 1.621 | 1.481 | 1.552 | 1.734 | 1.793 | 1.423 |
| Cr | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.002 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 |
| Fe3+ | 0.005 | 0.006 | 0.006 | 0.006 | 0.004 | 0.006 | 0.011 | 0.005 | 0.012 | 0.022 | 0.003 | 0.014 | 0.021 | 0.005 | 0.010 | 0.027 | 0.012 | 0.006 |
| Fe2+ | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Mn | 0.001 | 0.001 | 0.000 | 0.002 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Mg | 0.000 | 0.001 | 0.001 | 0.001 | 0.000 | 0.001 | 0.001 | 0.001 | 0.000 | 0.002 | 0.001 | 0.001 | 0.010 | 0.000 | 0.001 | 0.000 | 0.001 | 0.002 |
| Ca | 0.357 | 0.525 | 0.537 | 0.592 | 0.357 | 0.337 | 0.520 | 0.510 | 0.557 | 0.429 | 0.446 | 0.601 | 0.693 | 0.545 | 0.604 | 0.783 | 0.826 | 0.488 |
| Na | 0.589 | 0.429 | 0.426 | 0.371 | 0.579 | 0.625 | 0.469 | 0.478 | 0.427 | 0.527 | 0.524 | 0.386 | 0.304 | 0.430 | 0.378 | 0.190 | 0.132 | 0.472 |
| K | 0.033 | 0.021 | 0.023 | 0.022 | 0.032 | 0.029 | 0.014 | 0.011 | 0.012 | 0.025 | 0.018 | 0.008 | 0.008 | 0.012 | 0.010 | 0.002 | 0.002 | 0.023 |
| XAn | 0.36 | 0.54 | 0.54 | 0.60 | 0.37 | 0.34 | 0.52 | 0.51 | 0.56 | 0.44 | 0.45 | 0.60 | 0.69 | 0.55 | 0.61 | 0.80 | 0.86 | 0.50 |
| SiO2 (wt%) | 57.07 | 55.59 | 51.34 | 53.70 | 53.26 | 47.57 | 48.71 | 56.29 | 53.98 | 54.33 | 49.63 | 53.41 | 48.41 | 46.20 | 46.54 | 54.55 | ||
| TiO2 | 0.00 | 0.00 | 0.00 | 0.01 | 0.04 | 0.00 | 0.00 | 0.01 | 0.00 | 0.01 | 0.00 | 0.01 | 0.01 | 0.00 | 0.00 | 0.04 | ||
| Al2O3 | 26.70 | 27.78 | 30.62 | 27.89 | 29.23 | 32.23 | 32.34 | 26.89 | 29.02 | 29.00 | 32.24 | 29.37 | 32.94 | 34.42 | 34.22 | 28.98 | ||
| Cr2O3 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.00 | 0.03 | 0.03 | 0.02 | 0.03 | 0.02 | 0.00 | 0.00 | 0.01 | 0.01 | 0.02 | ||
| FeO | 0.13 | 0.12 | 0.33 | 0.15 | 0.00 | 0.80 | 0.30 | 0.37 | 0.12 | 0.16 | 0.17 | 0.12 | 0.17 | 0.35 | 0.30 | 0.09 | ||
| MnO | 0.00 | 0.03 | 0.00 | 0.01 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 | 0.02 | 0.01 | 0.02 | 0.00 | 0.02 | 0.04 | ||
| MgO | 0.02 | 0.00 | 0.01 | 0.02 | 0.14 | 0.55 | 0.01 | 0.01 | 0.02 | 0.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 | ||
| CaO | 9.55 | 11.07 | 14.57 | 10.84 | 12.13 | 15.19 | 16.12 | 9.56 | 10.75 | 10.88 | 14.82 | 11.19 | 15.13 | 17.32 | 17.19 | 10.92 | ||
| Na2O | 5.64 | 4.61 | 2.97 | 5.00 | 4.38 | 2.43 | 1.96 | 5.71 | 5.06 | 4.66 | 2.85 | 4.56 | 2.58 | 1.39 | 1.54 | 4.70 | ||
| K2O | 0.40 | 0.30 | 0.10 | 0.34 | 0.27 | 0.13 | 0.08 | 0.44 | 0.43 | 0.38 | 0.16 | 0.33 | 0.11 | 0.04 | 0.06 | 0.34 | ||
| Total | 99.52 | 99.56 | 99.98 | 97.98 | ##### | 98.99 | 99.58 | 99.35 | 99.40 | 99.50 | 99.94 | 99.01 | 99.38 | 99.77 | 99.91 | 99.69 | ||
| O cations | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | ||
| Si (p.f.u.) | 2.572 | 2.512 | 2.336 | 2.474 | 2.410 | 2.204 | 2.236 | 2.548 | 2.451 | 2.460 | 2.265 | 2.434 | 2.225 | 2.128 | 2.140 | 2.465 | ||
| Ti | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Al | 1.419 | 1.480 | 1.643 | 1.515 | 1.559 | 1.760 | 1.750 | 1.435 | 1.553 | 1.548 | 1.735 | 1.578 | 1.785 | 1.870 | 1.856 | 1.544 | ||
| Cr | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Fe3+ | 0.005 | 0.006 | 0.013 | 0.006 | 0.026 | 0.031 | 0.012 | 0.014 | 0.004 | 0.006 | 0.007 | 0.004 | 0.006 | 0.013 | 0.012 | 0.003 | ||
| Fe2+ | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | ||
| Mn | 0.000 | 0.001 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.001 | 0.001 | ||
| Mg | 0.001 | 0.000 | 0.001 | 0.001 | 0.009 | 0.038 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Ca | 0.461 | 0.536 | 0.710 | 0.535 | 0.588 | 0.754 | 0.793 | 0.464 | 0.523 | 0.528 | 0.725 | 0.546 | 0.745 | 0.855 | 0.847 | 0.529 | ||
| Na | 0.493 | 0.404 | 0.262 | 0.447 | 0.384 | 0.218 | 0.174 | 0.501 | 0.446 | 0.409 | 0.252 | 0.403 | 0.230 | 0.124 | 0.137 | 0.412 | ||
| K | 0.023 | 0.017 | 0.006 | 0.020 | 0.016 | 0.008 | 0.005 | 0.025 | 0.025 | 0.022 | 0.009 | 0.019 | 0.007 | 0.002 | 0.004 | 0.020 | ||
| XAn | 0.47 | 0.56 | 0.73 | 0.53 | 0.60 | 0.77 | 0.82 | 0.47 | 0.53 | 0.55 | 0.74 | 0.56 | 0.76 | 0.87 | 0.86 | 0.55 | ||
Total iron as FeO. XAn = Ca/(Ca + Na + K). Incl., inclusion.
| Sample . | TKL02-2 . | . | TKL18-4 . | . | MS02-3 . | |||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Mineral . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . |
| Texture | Pl-1 | Pl-2 | Incl. | Pl-1 | Pl-2 | Incl. | Pl-1 | Pl-2 | Pl-s1 | Pl-s2 | Incl. | |||||||
| Domain | core | rim | core | rim | core | rim | core | rim | core | mantle | rim | core | rim | |||||
| SiO2 (wt%) | 58.92 | 55.70 | 54.25 | 53.75 | 59.16 | 59.22 | 54.25 | 54.98 | 54.82 | 57.06 | 57.24 | 53.69 | 50.99 | 55.49 | 53.24 | 48.57 | 47.86 | 56.67 |
| TiO2 | 0.01 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.04 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| Al2O3 | 25.34 | 27.59 | 28.56 | 28.83 | 25.33 | 25.16 | 28.47 | 28.12 | 28.06 | 26.16 | 26.54 | 28.69 | 29.96 | 27.85 | 28.86 | 31.89 | 33.10 | 26.72 |
| Cr2O3 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.05 | 0.00 | 0.00 | 0.04 | 0.01 | 0.03 | 0.00 | 0.01 | 0.03 | 0.00 | 0.02 | 0.00 |
| FeO | 0.12 | 0.15 | 0.16 | 0.15 | 0.11 | 0.16 | 0.30 | 0.13 | 0.31 | 0.58 | 0.08 | 0.37 | 0.54 | 0.14 | 0.25 | 0.71 | 0.31 | 0.17 |
| MnO | 0.02 | 0.03 | 0.00 | 0.05 | 0.00 | 0.01 | 0.00 | 0.00 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.01 | 0.01 | 0.00 | 0.01 | 0.00 |
| MgO | 0.00 | 0.02 | 0.01 | 0.01 | 0.00 | 0.01 | 0.01 | 0.01 | 0.00 | 0.03 | 0.02 | 0.01 | 0.14 | 0.00 | 0.01 | 0.00 | 0.01 | 0.03 |
| CaO | 7.39 | 10.85 | 11.03 | 12.17 | 7.41 | 6.99 | 10.67 | 10.51 | 11.48 | 8.85 | 9.24 | 12.35 | 14.10 | 11.28 | 12.35 | 15.84 | 16.78 | 10.08 |
| Na2O | 6.75 | 4.90 | 4.83 | 4.21 | 6.64 | 7.17 | 5.32 | 5.44 | 4.87 | 6.01 | 5.99 | 4.39 | 3.42 | 4.92 | 4.27 | 2.12 | 1.48 | 5.39 |
| K2O | 0.57 | 0.37 | 0.39 | 0.38 | 0.56 | 0.50 | 0.25 | 0.19 | 0.20 | 0.42 | 0.31 | 0.14 | 0.14 | 0.21 | 0.18 | 0.04 | 0.03 | 0.40 |
| Total | 99.13 | 99.63 | 99.28 | 99.57 | 99.22 | 99.25 | 99.35 | 99.39 | 99.77 | 99.29 | 99.44 | 99.74 | 99.35 | 99.93 | 99.23 | 99.25 | 99.63 | 99.48 |
| O cations | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 |
| Si (p.f.u.) | 2.653 | 2.517 | 2.466 | 2.442 | 2.659 | 2.663 | 2.465 | 2.492 | 2.481 | 2.581 | 2.580 | 2.437 | 2.340 | 2.502 | 2.429 | 2.240 | 2.199 | 2.559 |
| Ti | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Al | 1.345 | 1.470 | 1.530 | 1.544 | 1.342 | 1.334 | 1.525 | 1.502 | 1.497 | 1.395 | 1.411 | 1.535 | 1.621 | 1.481 | 1.552 | 1.734 | 1.793 | 1.423 |
| Cr | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.002 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 |
| Fe3+ | 0.005 | 0.006 | 0.006 | 0.006 | 0.004 | 0.006 | 0.011 | 0.005 | 0.012 | 0.022 | 0.003 | 0.014 | 0.021 | 0.005 | 0.010 | 0.027 | 0.012 | 0.006 |
| Fe2+ | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Mn | 0.001 | 0.001 | 0.000 | 0.002 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Mg | 0.000 | 0.001 | 0.001 | 0.001 | 0.000 | 0.001 | 0.001 | 0.001 | 0.000 | 0.002 | 0.001 | 0.001 | 0.010 | 0.000 | 0.001 | 0.000 | 0.001 | 0.002 |
| Ca | 0.357 | 0.525 | 0.537 | 0.592 | 0.357 | 0.337 | 0.520 | 0.510 | 0.557 | 0.429 | 0.446 | 0.601 | 0.693 | 0.545 | 0.604 | 0.783 | 0.826 | 0.488 |
| Na | 0.589 | 0.429 | 0.426 | 0.371 | 0.579 | 0.625 | 0.469 | 0.478 | 0.427 | 0.527 | 0.524 | 0.386 | 0.304 | 0.430 | 0.378 | 0.190 | 0.132 | 0.472 |
| K | 0.033 | 0.021 | 0.023 | 0.022 | 0.032 | 0.029 | 0.014 | 0.011 | 0.012 | 0.025 | 0.018 | 0.008 | 0.008 | 0.012 | 0.010 | 0.002 | 0.002 | 0.023 |
| XAn | 0.36 | 0.54 | 0.54 | 0.60 | 0.37 | 0.34 | 0.52 | 0.51 | 0.56 | 0.44 | 0.45 | 0.60 | 0.69 | 0.55 | 0.61 | 0.80 | 0.86 | 0.50 |
| SiO2 (wt%) | 57.07 | 55.59 | 51.34 | 53.70 | 53.26 | 47.57 | 48.71 | 56.29 | 53.98 | 54.33 | 49.63 | 53.41 | 48.41 | 46.20 | 46.54 | 54.55 | ||
| TiO2 | 0.00 | 0.00 | 0.00 | 0.01 | 0.04 | 0.00 | 0.00 | 0.01 | 0.00 | 0.01 | 0.00 | 0.01 | 0.01 | 0.00 | 0.00 | 0.04 | ||
| Al2O3 | 26.70 | 27.78 | 30.62 | 27.89 | 29.23 | 32.23 | 32.34 | 26.89 | 29.02 | 29.00 | 32.24 | 29.37 | 32.94 | 34.42 | 34.22 | 28.98 | ||
| Cr2O3 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.00 | 0.03 | 0.03 | 0.02 | 0.03 | 0.02 | 0.00 | 0.00 | 0.01 | 0.01 | 0.02 | ||
| FeO | 0.13 | 0.12 | 0.33 | 0.15 | 0.00 | 0.80 | 0.30 | 0.37 | 0.12 | 0.16 | 0.17 | 0.12 | 0.17 | 0.35 | 0.30 | 0.09 | ||
| MnO | 0.00 | 0.03 | 0.00 | 0.01 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 | 0.02 | 0.01 | 0.02 | 0.00 | 0.02 | 0.04 | ||
| MgO | 0.02 | 0.00 | 0.01 | 0.02 | 0.14 | 0.55 | 0.01 | 0.01 | 0.02 | 0.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 | ||
| CaO | 9.55 | 11.07 | 14.57 | 10.84 | 12.13 | 15.19 | 16.12 | 9.56 | 10.75 | 10.88 | 14.82 | 11.19 | 15.13 | 17.32 | 17.19 | 10.92 | ||
| Na2O | 5.64 | 4.61 | 2.97 | 5.00 | 4.38 | 2.43 | 1.96 | 5.71 | 5.06 | 4.66 | 2.85 | 4.56 | 2.58 | 1.39 | 1.54 | 4.70 | ||
| K2O | 0.40 | 0.30 | 0.10 | 0.34 | 0.27 | 0.13 | 0.08 | 0.44 | 0.43 | 0.38 | 0.16 | 0.33 | 0.11 | 0.04 | 0.06 | 0.34 | ||
| Total | 99.52 | 99.56 | 99.98 | 97.98 | ##### | 98.99 | 99.58 | 99.35 | 99.40 | 99.50 | 99.94 | 99.01 | 99.38 | 99.77 | 99.91 | 99.69 | ||
| O cations | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | ||
| Si (p.f.u.) | 2.572 | 2.512 | 2.336 | 2.474 | 2.410 | 2.204 | 2.236 | 2.548 | 2.451 | 2.460 | 2.265 | 2.434 | 2.225 | 2.128 | 2.140 | 2.465 | ||
| Ti | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Al | 1.419 | 1.480 | 1.643 | 1.515 | 1.559 | 1.760 | 1.750 | 1.435 | 1.553 | 1.548 | 1.735 | 1.578 | 1.785 | 1.870 | 1.856 | 1.544 | ||
| Cr | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Fe3+ | 0.005 | 0.006 | 0.013 | 0.006 | 0.026 | 0.031 | 0.012 | 0.014 | 0.004 | 0.006 | 0.007 | 0.004 | 0.006 | 0.013 | 0.012 | 0.003 | ||
| Fe2+ | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | ||
| Mn | 0.000 | 0.001 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.001 | 0.001 | ||
| Mg | 0.001 | 0.000 | 0.001 | 0.001 | 0.009 | 0.038 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Ca | 0.461 | 0.536 | 0.710 | 0.535 | 0.588 | 0.754 | 0.793 | 0.464 | 0.523 | 0.528 | 0.725 | 0.546 | 0.745 | 0.855 | 0.847 | 0.529 | ||
| Na | 0.493 | 0.404 | 0.262 | 0.447 | 0.384 | 0.218 | 0.174 | 0.501 | 0.446 | 0.409 | 0.252 | 0.403 | 0.230 | 0.124 | 0.137 | 0.412 | ||
| K | 0.023 | 0.017 | 0.006 | 0.020 | 0.016 | 0.008 | 0.005 | 0.025 | 0.025 | 0.022 | 0.009 | 0.019 | 0.007 | 0.002 | 0.004 | 0.020 | ||
| XAn | 0.47 | 0.56 | 0.73 | 0.53 | 0.60 | 0.77 | 0.82 | 0.47 | 0.53 | 0.55 | 0.74 | 0.56 | 0.76 | 0.87 | 0.86 | 0.55 | ||
| Sample . | TKL02-2 . | . | TKL18-4 . | . | MS02-3 . | |||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Mineral . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . | Pl . |
| Texture | Pl-1 | Pl-2 | Incl. | Pl-1 | Pl-2 | Incl. | Pl-1 | Pl-2 | Pl-s1 | Pl-s2 | Incl. | |||||||
| Domain | core | rim | core | rim | core | rim | core | rim | core | mantle | rim | core | rim | |||||
| SiO2 (wt%) | 58.92 | 55.70 | 54.25 | 53.75 | 59.16 | 59.22 | 54.25 | 54.98 | 54.82 | 57.06 | 57.24 | 53.69 | 50.99 | 55.49 | 53.24 | 48.57 | 47.86 | 56.67 |
| TiO2 | 0.01 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.04 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 |
| Al2O3 | 25.34 | 27.59 | 28.56 | 28.83 | 25.33 | 25.16 | 28.47 | 28.12 | 28.06 | 26.16 | 26.54 | 28.69 | 29.96 | 27.85 | 28.86 | 31.89 | 33.10 | 26.72 |
| Cr2O3 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.05 | 0.00 | 0.00 | 0.04 | 0.01 | 0.03 | 0.00 | 0.01 | 0.03 | 0.00 | 0.02 | 0.00 |
| FeO | 0.12 | 0.15 | 0.16 | 0.15 | 0.11 | 0.16 | 0.30 | 0.13 | 0.31 | 0.58 | 0.08 | 0.37 | 0.54 | 0.14 | 0.25 | 0.71 | 0.31 | 0.17 |
| MnO | 0.02 | 0.03 | 0.00 | 0.05 | 0.00 | 0.01 | 0.00 | 0.00 | 0.00 | 0.03 | 0.00 | 0.00 | 0.00 | 0.01 | 0.01 | 0.00 | 0.01 | 0.00 |
| MgO | 0.00 | 0.02 | 0.01 | 0.01 | 0.00 | 0.01 | 0.01 | 0.01 | 0.00 | 0.03 | 0.02 | 0.01 | 0.14 | 0.00 | 0.01 | 0.00 | 0.01 | 0.03 |
| CaO | 7.39 | 10.85 | 11.03 | 12.17 | 7.41 | 6.99 | 10.67 | 10.51 | 11.48 | 8.85 | 9.24 | 12.35 | 14.10 | 11.28 | 12.35 | 15.84 | 16.78 | 10.08 |
| Na2O | 6.75 | 4.90 | 4.83 | 4.21 | 6.64 | 7.17 | 5.32 | 5.44 | 4.87 | 6.01 | 5.99 | 4.39 | 3.42 | 4.92 | 4.27 | 2.12 | 1.48 | 5.39 |
| K2O | 0.57 | 0.37 | 0.39 | 0.38 | 0.56 | 0.50 | 0.25 | 0.19 | 0.20 | 0.42 | 0.31 | 0.14 | 0.14 | 0.21 | 0.18 | 0.04 | 0.03 | 0.40 |
| Total | 99.13 | 99.63 | 99.28 | 99.57 | 99.22 | 99.25 | 99.35 | 99.39 | 99.77 | 99.29 | 99.44 | 99.74 | 99.35 | 99.93 | 99.23 | 99.25 | 99.63 | 99.48 |
| O cations | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 |
| Si (p.f.u.) | 2.653 | 2.517 | 2.466 | 2.442 | 2.659 | 2.663 | 2.465 | 2.492 | 2.481 | 2.581 | 2.580 | 2.437 | 2.340 | 2.502 | 2.429 | 2.240 | 2.199 | 2.559 |
| Ti | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Al | 1.345 | 1.470 | 1.530 | 1.544 | 1.342 | 1.334 | 1.525 | 1.502 | 1.497 | 1.395 | 1.411 | 1.535 | 1.621 | 1.481 | 1.552 | 1.734 | 1.793 | 1.423 |
| Cr | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.002 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 | 0.000 | 0.001 | 0.000 | 0.001 | 0.000 |
| Fe3+ | 0.005 | 0.006 | 0.006 | 0.006 | 0.004 | 0.006 | 0.011 | 0.005 | 0.012 | 0.022 | 0.003 | 0.014 | 0.021 | 0.005 | 0.010 | 0.027 | 0.012 | 0.006 |
| Fe2+ | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Mn | 0.001 | 0.001 | 0.000 | 0.002 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 |
| Mg | 0.000 | 0.001 | 0.001 | 0.001 | 0.000 | 0.001 | 0.001 | 0.001 | 0.000 | 0.002 | 0.001 | 0.001 | 0.010 | 0.000 | 0.001 | 0.000 | 0.001 | 0.002 |
| Ca | 0.357 | 0.525 | 0.537 | 0.592 | 0.357 | 0.337 | 0.520 | 0.510 | 0.557 | 0.429 | 0.446 | 0.601 | 0.693 | 0.545 | 0.604 | 0.783 | 0.826 | 0.488 |
| Na | 0.589 | 0.429 | 0.426 | 0.371 | 0.579 | 0.625 | 0.469 | 0.478 | 0.427 | 0.527 | 0.524 | 0.386 | 0.304 | 0.430 | 0.378 | 0.190 | 0.132 | 0.472 |
| K | 0.033 | 0.021 | 0.023 | 0.022 | 0.032 | 0.029 | 0.014 | 0.011 | 0.012 | 0.025 | 0.018 | 0.008 | 0.008 | 0.012 | 0.010 | 0.002 | 0.002 | 0.023 |
| XAn | 0.36 | 0.54 | 0.54 | 0.60 | 0.37 | 0.34 | 0.52 | 0.51 | 0.56 | 0.44 | 0.45 | 0.60 | 0.69 | 0.55 | 0.61 | 0.80 | 0.86 | 0.50 |
| SiO2 (wt%) | 57.07 | 55.59 | 51.34 | 53.70 | 53.26 | 47.57 | 48.71 | 56.29 | 53.98 | 54.33 | 49.63 | 53.41 | 48.41 | 46.20 | 46.54 | 54.55 | ||
| TiO2 | 0.00 | 0.00 | 0.00 | 0.01 | 0.04 | 0.00 | 0.00 | 0.01 | 0.00 | 0.01 | 0.00 | 0.01 | 0.01 | 0.00 | 0.00 | 0.04 | ||
| Al2O3 | 26.70 | 27.78 | 30.62 | 27.89 | 29.23 | 32.23 | 32.34 | 26.89 | 29.02 | 29.00 | 32.24 | 29.37 | 32.94 | 34.42 | 34.22 | 28.98 | ||
| Cr2O3 | 0.00 | 0.00 | 0.00 | 0.00 | 0.01 | 0.00 | 0.03 | 0.03 | 0.02 | 0.03 | 0.02 | 0.00 | 0.00 | 0.01 | 0.01 | 0.02 | ||
| FeO | 0.13 | 0.12 | 0.33 | 0.15 | 0.00 | 0.80 | 0.30 | 0.37 | 0.12 | 0.16 | 0.17 | 0.12 | 0.17 | 0.35 | 0.30 | 0.09 | ||
| MnO | 0.00 | 0.03 | 0.00 | 0.01 | 0.03 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 | 0.02 | 0.01 | 0.02 | 0.00 | 0.02 | 0.04 | ||
| MgO | 0.02 | 0.00 | 0.01 | 0.02 | 0.14 | 0.55 | 0.01 | 0.01 | 0.02 | 0.01 | 0.00 | 0.00 | 0.00 | 0.00 | 0.00 | 0.02 | ||
| CaO | 9.55 | 11.07 | 14.57 | 10.84 | 12.13 | 15.19 | 16.12 | 9.56 | 10.75 | 10.88 | 14.82 | 11.19 | 15.13 | 17.32 | 17.19 | 10.92 | ||
| Na2O | 5.64 | 4.61 | 2.97 | 5.00 | 4.38 | 2.43 | 1.96 | 5.71 | 5.06 | 4.66 | 2.85 | 4.56 | 2.58 | 1.39 | 1.54 | 4.70 | ||
| K2O | 0.40 | 0.30 | 0.10 | 0.34 | 0.27 | 0.13 | 0.08 | 0.44 | 0.43 | 0.38 | 0.16 | 0.33 | 0.11 | 0.04 | 0.06 | 0.34 | ||
| Total | 99.52 | 99.56 | 99.98 | 97.98 | ##### | 98.99 | 99.58 | 99.35 | 99.40 | 99.50 | 99.94 | 99.01 | 99.38 | 99.77 | 99.91 | 99.69 | ||
| O cations | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | 8 | ||
| Si (p.f.u.) | 2.572 | 2.512 | 2.336 | 2.474 | 2.410 | 2.204 | 2.236 | 2.548 | 2.451 | 2.460 | 2.265 | 2.434 | 2.225 | 2.128 | 2.140 | 2.465 | ||
| Ti | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Al | 1.419 | 1.480 | 1.643 | 1.515 | 1.559 | 1.760 | 1.750 | 1.435 | 1.553 | 1.548 | 1.735 | 1.578 | 1.785 | 1.870 | 1.856 | 1.544 | ||
| Cr | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Fe3+ | 0.005 | 0.006 | 0.013 | 0.006 | 0.026 | 0.031 | 0.012 | 0.014 | 0.004 | 0.006 | 0.007 | 0.004 | 0.006 | 0.013 | 0.012 | 0.003 | ||
| Fe2+ | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | ||
| Mn | 0.000 | 0.001 | 0.000 | 0.000 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.001 | 0.001 | ||
| Mg | 0.001 | 0.000 | 0.001 | 0.001 | 0.009 | 0.038 | 0.001 | 0.001 | 0.001 | 0.001 | 0.000 | 0.000 | 0.000 | 0.000 | 0.000 | 0.001 | ||
| Ca | 0.461 | 0.536 | 0.710 | 0.535 | 0.588 | 0.754 | 0.793 | 0.464 | 0.523 | 0.528 | 0.725 | 0.546 | 0.745 | 0.855 | 0.847 | 0.529 | ||
| Na | 0.493 | 0.404 | 0.262 | 0.447 | 0.384 | 0.218 | 0.174 | 0.501 | 0.446 | 0.409 | 0.252 | 0.403 | 0.230 | 0.124 | 0.137 | 0.412 | ||
| K | 0.023 | 0.017 | 0.006 | 0.020 | 0.016 | 0.008 | 0.005 | 0.025 | 0.025 | 0.022 | 0.009 | 0.019 | 0.007 | 0.002 | 0.004 | 0.020 | ||
| XAn | 0.47 | 0.56 | 0.73 | 0.53 | 0.60 | 0.77 | 0.82 | 0.47 | 0.53 | 0.55 | 0.74 | 0.56 | 0.76 | 0.87 | 0.86 | 0.55 | ||
Total iron as FeO. XAn = Ca/(Ca + Na + K). Incl., inclusion.
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