Comparison of theoretically predicted 39K35Cl ro-vibrational wavenumbers, in cm−1, with some of the laboratory data of Ram et al. (1997), as re-assigned in this work.
| v′ . | J′ . | v′′ . | J′′ . | Obs. . | Calc. . | Obs.−Calc. . |
|---|---|---|---|---|---|---|
| 1 | 102 | 0 | 101 | 294.9349 | 294.9347 | 0.0002 |
| 1 | 103 | 0 | 102 | 295.0173 | 295.0154 | 0.0019 |
| 1 | 104 | 0 | 103 | 295.0955 | 295.0941 | 0.0014 |
| 1 | 105 | 0 | 104 | 295.1729 | 295.1710 | 0.0019 |
| 2 | 43 | 1 | 42 | 284.5787 | 284.5795 | −0.0008 |
| 2 | 49 | 1 | 48 | 285.6588 | 285.6551 | 0.0037 |
| 2 | 51 | 1 | 50 | 286.0004 | 286.0001 | 0.0003 |
| 2 | 52 | 1 | 51 | 286.1646 | 286.1700 | −0.0054 |
| 3 | 121 | 2 | 120 | 291.1544 | 291.1554 | −0.0010 |
| 3 | 122 | 2 | 121 | 291.2013 | 291.1992 | 0.0021 |
| 3 | 123 | 2 | 122 | 291.2433 | 291.2411 | 0.0022 |
| 3 | 126 | 2 | 125 | 291.3562 | 291.3555 | 0.0007 |
| 4 | 74 | 3 | 73 | 284.6069 | 284.6019 | 0.0050 |
| 4 | 75 | 3 | 74 | 284.7309 | 284.7300 | 0.0009 |
| 4 | 76 | 3 | 75 | 284.8579 | 284.8563 | 0.0016 |
| 4 | 78 | 3 | 77 | 285.1054 | 285.1036 | 0.0018 |
| 5 | 111 | 4 | 110 | 285.7192 | 285.7174 | 0.0018 |
| 5 | 113 | 4 | 112 | 285.8341 | 285.8375 | −0.0034 |
| 5 | 114 | 4 | 113 | 285.8912 | 285.8947 | −0.0035 |
| 5 | 116 | 4 | 115 | 286.0004 | 286.0037 | −0.0033 |
| 6 | 73 | 5 | 72 | 279.6821 | 279.6817 | 0.0004 |
| 6 | 75 | 5 | 74 | 279.9388 | 279.9355 | 0.0033 |
| 6 | 76 | 5 | 75 | 280.0552 | 280.0598 | −0.0047 |
| 6 | 81 | 5 | 80 | 280.6586 | 280.6552 | 0.0034 |
| v′ . | J′ . | v′′ . | J′′ . | Obs. . | Calc. . | Obs.−Calc. . |
|---|---|---|---|---|---|---|
| 1 | 102 | 0 | 101 | 294.9349 | 294.9347 | 0.0002 |
| 1 | 103 | 0 | 102 | 295.0173 | 295.0154 | 0.0019 |
| 1 | 104 | 0 | 103 | 295.0955 | 295.0941 | 0.0014 |
| 1 | 105 | 0 | 104 | 295.1729 | 295.1710 | 0.0019 |
| 2 | 43 | 1 | 42 | 284.5787 | 284.5795 | −0.0008 |
| 2 | 49 | 1 | 48 | 285.6588 | 285.6551 | 0.0037 |
| 2 | 51 | 1 | 50 | 286.0004 | 286.0001 | 0.0003 |
| 2 | 52 | 1 | 51 | 286.1646 | 286.1700 | −0.0054 |
| 3 | 121 | 2 | 120 | 291.1544 | 291.1554 | −0.0010 |
| 3 | 122 | 2 | 121 | 291.2013 | 291.1992 | 0.0021 |
| 3 | 123 | 2 | 122 | 291.2433 | 291.2411 | 0.0022 |
| 3 | 126 | 2 | 125 | 291.3562 | 291.3555 | 0.0007 |
| 4 | 74 | 3 | 73 | 284.6069 | 284.6019 | 0.0050 |
| 4 | 75 | 3 | 74 | 284.7309 | 284.7300 | 0.0009 |
| 4 | 76 | 3 | 75 | 284.8579 | 284.8563 | 0.0016 |
| 4 | 78 | 3 | 77 | 285.1054 | 285.1036 | 0.0018 |
| 5 | 111 | 4 | 110 | 285.7192 | 285.7174 | 0.0018 |
| 5 | 113 | 4 | 112 | 285.8341 | 285.8375 | −0.0034 |
| 5 | 114 | 4 | 113 | 285.8912 | 285.8947 | −0.0035 |
| 5 | 116 | 4 | 115 | 286.0004 | 286.0037 | −0.0033 |
| 6 | 73 | 5 | 72 | 279.6821 | 279.6817 | 0.0004 |
| 6 | 75 | 5 | 74 | 279.9388 | 279.9355 | 0.0033 |
| 6 | 76 | 5 | 75 | 280.0552 | 280.0598 | −0.0047 |
| 6 | 81 | 5 | 80 | 280.6586 | 280.6552 | 0.0034 |
Comparison of theoretically predicted 39K35Cl ro-vibrational wavenumbers, in cm−1, with some of the laboratory data of Ram et al. (1997), as re-assigned in this work.
| v′ . | J′ . | v′′ . | J′′ . | Obs. . | Calc. . | Obs.−Calc. . |
|---|---|---|---|---|---|---|
| 1 | 102 | 0 | 101 | 294.9349 | 294.9347 | 0.0002 |
| 1 | 103 | 0 | 102 | 295.0173 | 295.0154 | 0.0019 |
| 1 | 104 | 0 | 103 | 295.0955 | 295.0941 | 0.0014 |
| 1 | 105 | 0 | 104 | 295.1729 | 295.1710 | 0.0019 |
| 2 | 43 | 1 | 42 | 284.5787 | 284.5795 | −0.0008 |
| 2 | 49 | 1 | 48 | 285.6588 | 285.6551 | 0.0037 |
| 2 | 51 | 1 | 50 | 286.0004 | 286.0001 | 0.0003 |
| 2 | 52 | 1 | 51 | 286.1646 | 286.1700 | −0.0054 |
| 3 | 121 | 2 | 120 | 291.1544 | 291.1554 | −0.0010 |
| 3 | 122 | 2 | 121 | 291.2013 | 291.1992 | 0.0021 |
| 3 | 123 | 2 | 122 | 291.2433 | 291.2411 | 0.0022 |
| 3 | 126 | 2 | 125 | 291.3562 | 291.3555 | 0.0007 |
| 4 | 74 | 3 | 73 | 284.6069 | 284.6019 | 0.0050 |
| 4 | 75 | 3 | 74 | 284.7309 | 284.7300 | 0.0009 |
| 4 | 76 | 3 | 75 | 284.8579 | 284.8563 | 0.0016 |
| 4 | 78 | 3 | 77 | 285.1054 | 285.1036 | 0.0018 |
| 5 | 111 | 4 | 110 | 285.7192 | 285.7174 | 0.0018 |
| 5 | 113 | 4 | 112 | 285.8341 | 285.8375 | −0.0034 |
| 5 | 114 | 4 | 113 | 285.8912 | 285.8947 | −0.0035 |
| 5 | 116 | 4 | 115 | 286.0004 | 286.0037 | −0.0033 |
| 6 | 73 | 5 | 72 | 279.6821 | 279.6817 | 0.0004 |
| 6 | 75 | 5 | 74 | 279.9388 | 279.9355 | 0.0033 |
| 6 | 76 | 5 | 75 | 280.0552 | 280.0598 | −0.0047 |
| 6 | 81 | 5 | 80 | 280.6586 | 280.6552 | 0.0034 |
| v′ . | J′ . | v′′ . | J′′ . | Obs. . | Calc. . | Obs.−Calc. . |
|---|---|---|---|---|---|---|
| 1 | 102 | 0 | 101 | 294.9349 | 294.9347 | 0.0002 |
| 1 | 103 | 0 | 102 | 295.0173 | 295.0154 | 0.0019 |
| 1 | 104 | 0 | 103 | 295.0955 | 295.0941 | 0.0014 |
| 1 | 105 | 0 | 104 | 295.1729 | 295.1710 | 0.0019 |
| 2 | 43 | 1 | 42 | 284.5787 | 284.5795 | −0.0008 |
| 2 | 49 | 1 | 48 | 285.6588 | 285.6551 | 0.0037 |
| 2 | 51 | 1 | 50 | 286.0004 | 286.0001 | 0.0003 |
| 2 | 52 | 1 | 51 | 286.1646 | 286.1700 | −0.0054 |
| 3 | 121 | 2 | 120 | 291.1544 | 291.1554 | −0.0010 |
| 3 | 122 | 2 | 121 | 291.2013 | 291.1992 | 0.0021 |
| 3 | 123 | 2 | 122 | 291.2433 | 291.2411 | 0.0022 |
| 3 | 126 | 2 | 125 | 291.3562 | 291.3555 | 0.0007 |
| 4 | 74 | 3 | 73 | 284.6069 | 284.6019 | 0.0050 |
| 4 | 75 | 3 | 74 | 284.7309 | 284.7300 | 0.0009 |
| 4 | 76 | 3 | 75 | 284.8579 | 284.8563 | 0.0016 |
| 4 | 78 | 3 | 77 | 285.1054 | 285.1036 | 0.0018 |
| 5 | 111 | 4 | 110 | 285.7192 | 285.7174 | 0.0018 |
| 5 | 113 | 4 | 112 | 285.8341 | 285.8375 | −0.0034 |
| 5 | 114 | 4 | 113 | 285.8912 | 285.8947 | −0.0035 |
| 5 | 116 | 4 | 115 | 286.0004 | 286.0037 | −0.0033 |
| 6 | 73 | 5 | 72 | 279.6821 | 279.6817 | 0.0004 |
| 6 | 75 | 5 | 74 | 279.9388 | 279.9355 | 0.0033 |
| 6 | 76 | 5 | 75 | 280.0552 | 280.0598 | −0.0047 |
| 6 | 81 | 5 | 80 | 280.6586 | 280.6552 | 0.0034 |
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