Table 2. Open in new tab Stark shifts d...

Experimental

Theoretical

Transition^a

Multiplet^a

λ (Å) ^a

d^b

d^c

d´^c

d^d

3d⁵(⁶S)4s–3d⁵(⁶S)4p

a⁷S–z⁷P^o

2576.104

0.21

−0.0401

−0.0669

−1.30

2593.721

0.24

−0.62

−0.0996

−0.0756

−1.30

2605.680

0.33

−0.92

−0.631

−0.0816

−1.30

a⁵S–z⁵P^o

2939.308

< 0.1

−1.5

−0.174

−0.244

−1.79

3d⁶–3d⁵(⁶S)4p

a⁵D–z⁵P^o

3495.833

3.6

3482.904

3.5

3488.675

3.5

3d⁵(⁴ G)4s–3d⁵(⁴ G)4p

a⁵G–z⁵G^o

2705.732

< 0.1

2708.452

< 0.1

a⁵G–z⁵H^o

2610.200

0.37

−0.62

2618.148

0.24

2625.606

0.14

a⁵G–z⁵F^o

2563.642

0.10

2565.219

< 0.1

3d⁵(⁴P)4s–3d⁵(⁴ G)4p

a⁵P–z⁵F^o

2716.796

< 0.1

3d⁵(⁴P)4s–3d⁵(⁴P)4p

a⁵P–z⁵D^o

2672.581

< 0.1

2724.465

−0.3

3d⁵(⁴P)4s–3d⁵(⁴D)4p

a⁵P –y⁵D^o

2373.357

0.4

3d⁶–3d⁵(⁴ G)4p

a³H–z³G^o

2507.598

2.7

a³F–z³F^o

2750.126

1.8

3d⁵(⁴D)4s –3d⁵(⁴D)4p

b⁵D–y⁵F^o

2639.849

0.2

3d⁵(⁴ G)4s–3d⁵(⁴ G)4p

a³G–z³H^o

2886.671

0.9

a³G–z³F^o

2892.389

0.9

a³G–z³G^o

2684.539

0.9

3d⁶–3d⁵(⁴ G)4p

b³G–z³G^o

2815.025

1.8

3d⁵(⁴P)4s–3d⁵(⁴P)4p

b³P–z³P^o

3050.654

−0.3

b³P–z³D^o

2900.154

0.1

2891.332

0.4

3d⁶–3d⁵(²I)4p

a¹I–z¹I^o

2320.420

1.9

3d⁵(²I)4s–3d⁵(²I)4p

b¹I–z¹K^o

2870.085

< 0.1

Table 2.

Open in new tab

Stark shifts d (pm) of Mn ii spectral lines at electron density 10¹⁷ cm⁻³ and for a temperature range of 11 000–13 900 K. The available data in the literature are shown for comparison. The estimated relative error of d is 11 per cent.

				Experimental		Theoretical
No	Transition^a	Multiplet^a	λ (Å) ^a	d	d^b	d^c	d´^c	d^d
1	3d⁵(⁶S)4s–3d⁵(⁶S)4p	a⁷S–z⁷P^o	2576.104	0.21		−0.0401	−0.0669	−1.30
			2593.721	0.24	−0.62	−0.0996	−0.0756	−1.30
			2605.680	0.33	−0.92	−0.631	−0.0816	−1.30
2		a⁵S–z⁵P^o	2939.308	< 0.1	−1.5	−0.174	−0.244	−1.79
3	3d⁶–3d⁵(⁶S)4p	a⁵D–z⁵P^o	3495.833	3.6
			3482.904	3.5
			3488.675	3.5
4	3d⁵(⁴ G)4s–3d⁵(⁴ G)4p	a⁵G–z⁵G^o	2705.732	< 0.1
			2708.452	< 0.1
5		a⁵G–z⁵H^o	2610.200	0.37	−0.62
			2618.148	0.24
			2625.606	0.14
6		a⁵G–z⁵F^o	2563.642	0.10
			2565.219	< 0.1
7	3d⁵(⁴P)4s–3d⁵(⁴ G)4p	a⁵P–z⁵F^o	2716.796	< 0.1
8	3d⁵(⁴P)4s–3d⁵(⁴P)4p	a⁵P–z⁵D^o	2672.581	< 0.1
			2724.465	−0.3
9	3d⁵(⁴P)4s–3d⁵(⁴D)4p	a⁵P –y⁵D^o	2373.357	0.4
10	3d⁶–3d⁵(⁴ G)4p	a³H–z³G^o	2507.598	2.7
11		a³F–z³F^o	2750.126	1.8
12	3d⁵(⁴D)4s –3d⁵(⁴D)4p	b⁵D–y⁵F^o	2639.849	0.2
13	3d⁵(⁴ G)4s–3d⁵(⁴ G)4p	a³G–z³H^o	2886.671	0.9
14		a³G–z³F^o	2892.389	0.9
15		a³G–z³G^o	2684.539	0.9
16	3d⁶–3d⁵(⁴ G)4p	b³G–z³G^o	2815.025	1.8
17	3d⁵(⁴P)4s–3d⁵(⁴P)4p	b³P–z³P^o	3050.654	−0.3
18		b³P–z³D^o	2900.154	0.1
			2891.332	0.4
19	3d⁶–3d⁵(²I)4p	a¹I–z¹I^o	2320.420	1.9
20	3d⁵(²I)4s–3d⁵(²I)4p	b¹I–z¹K^o	2870.085	< 0.1

				Experimental		Theoretical
No	Transition^a	Multiplet^a	λ (Å) ^a	d	d^b	d^c	d´^c	d^d
1	3d⁵(⁶S)4s–3d⁵(⁶S)4p	a⁷S–z⁷P^o	2576.104	0.21		−0.0401	−0.0669	−1.30
			2593.721	0.24	−0.62	−0.0996	−0.0756	−1.30
			2605.680	0.33	−0.92	−0.631	−0.0816	−1.30
2		a⁵S–z⁵P^o	2939.308	< 0.1	−1.5	−0.174	−0.244	−1.79
3	3d⁶–3d⁵(⁶S)4p	a⁵D–z⁵P^o	3495.833	3.6
			3482.904	3.5
			3488.675	3.5
4	3d⁵(⁴ G)4s–3d⁵(⁴ G)4p	a⁵G–z⁵G^o	2705.732	< 0.1
			2708.452	< 0.1
5		a⁵G–z⁵H^o	2610.200	0.37	−0.62
			2618.148	0.24
			2625.606	0.14
6		a⁵G–z⁵F^o	2563.642	0.10
			2565.219	< 0.1
7	3d⁵(⁴P)4s–3d⁵(⁴ G)4p	a⁵P–z⁵F^o	2716.796	< 0.1
8	3d⁵(⁴P)4s–3d⁵(⁴P)4p	a⁵P–z⁵D^o	2672.581	< 0.1
			2724.465	−0.3
9	3d⁵(⁴P)4s–3d⁵(⁴D)4p	a⁵P –y⁵D^o	2373.357	0.4
10	3d⁶–3d⁵(⁴ G)4p	a³H–z³G^o	2507.598	2.7
11		a³F–z³F^o	2750.126	1.8
12	3d⁵(⁴D)4s –3d⁵(⁴D)4p	b⁵D–y⁵F^o	2639.849	0.2
13	3d⁵(⁴ G)4s–3d⁵(⁴ G)4p	a³G–z³H^o	2886.671	0.9
14		a³G–z³F^o	2892.389	0.9
15		a³G–z³G^o	2684.539	0.9
16	3d⁶–3d⁵(⁴ G)4p	b³G–z³G^o	2815.025	1.8
17	3d⁵(⁴P)4s–3d⁵(⁴P)4p	b³P–z³P^o	3050.654	−0.3
18		b³P–z³D^o	2900.154	0.1
			2891.332	0.4
19	3d⁶–3d⁵(²I)4p	a¹I–z¹I^o	2320.420	1.9
20	3d⁵(²I)4s–3d⁵(²I)4p	b¹I–z¹K^o	2870.085	< 0.1

^aData from Kramida et al. (2018).

^bDjeniže et al. (2006). Data reported for a temperature of 49 000 K.

^cPopović et al (2008). The d value is calculated including contributions from allowed and forbidden transitions; the d´ value is calculated including only dipole allowed transitions. Data reported for a temperature of 10 000 K.

^dPopović & Dimitrijević (1997). Data reported for a temperature of 10 000 K.

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