Calculated and experimental (Ulenikov et al. 2002) k = 7 and k = 8, A1 − A2 splittings (in MHz) and their sensitivities in the ν3 vibrational state of PH3.
J . | νexp . | νcalc . | T . | νexp . | νcalc . | T . |
---|---|---|---|---|---|---|
k = 7 | k = 8 | |||||
12 | 30.55 | −64 | 1340 | 743.7 | −91 | |
13 | 1260170 | 1.44 | 18210 | 34 | ||
14 | 1817 | 8766 | 0.21 | 3136 | 10565 | −4.91 |
15 | 2585.5 | 27.6 | 1344.4 | −22.3 | ||
16 | 807.4 | −1.11 | 1370.2 | 11.7 | ||
17 | 1485.1 | −22.9 | 5056.4 | −16.8 | ||
18 | 1315.0 | −417 | 73.0 | −3.1 |
J . | νexp . | νcalc . | T . | νexp . | νcalc . | T . |
---|---|---|---|---|---|---|
k = 7 | k = 8 | |||||
12 | 30.55 | −64 | 1340 | 743.7 | −91 | |
13 | 1260170 | 1.44 | 18210 | 34 | ||
14 | 1817 | 8766 | 0.21 | 3136 | 10565 | −4.91 |
15 | 2585.5 | 27.6 | 1344.4 | −22.3 | ||
16 | 807.4 | −1.11 | 1370.2 | 11.7 | ||
17 | 1485.1 | −22.9 | 5056.4 | −16.8 | ||
18 | 1315.0 | −417 | 73.0 | −3.1 |
Calculated and experimental (Ulenikov et al. 2002) k = 7 and k = 8, A1 − A2 splittings (in MHz) and their sensitivities in the ν3 vibrational state of PH3.
J . | νexp . | νcalc . | T . | νexp . | νcalc . | T . |
---|---|---|---|---|---|---|
k = 7 | k = 8 | |||||
12 | 30.55 | −64 | 1340 | 743.7 | −91 | |
13 | 1260170 | 1.44 | 18210 | 34 | ||
14 | 1817 | 8766 | 0.21 | 3136 | 10565 | −4.91 |
15 | 2585.5 | 27.6 | 1344.4 | −22.3 | ||
16 | 807.4 | −1.11 | 1370.2 | 11.7 | ||
17 | 1485.1 | −22.9 | 5056.4 | −16.8 | ||
18 | 1315.0 | −417 | 73.0 | −3.1 |
J . | νexp . | νcalc . | T . | νexp . | νcalc . | T . |
---|---|---|---|---|---|---|
k = 7 | k = 8 | |||||
12 | 30.55 | −64 | 1340 | 743.7 | −91 | |
13 | 1260170 | 1.44 | 18210 | 34 | ||
14 | 1817 | 8766 | 0.21 | 3136 | 10565 | −4.91 |
15 | 2585.5 | 27.6 | 1344.4 | −22.3 | ||
16 | 807.4 | −1.11 | 1370.2 | 11.7 | ||
17 | 1485.1 | −22.9 | 5056.4 | −16.8 | ||
18 | 1315.0 | −417 | 73.0 | −3.1 |
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