Table 5. Open in new tab Calculated and... | Oxford Academic

Table 5.

Open in new tab

Calculated and experimental (Ulenikov et al. 2002) k = 1 and k = 2, A₁ − A₂ splittings (in MHz) and their sensitivities in the ν₃ vibrational state of PH₃.

J	ν_exp	ν_calc	T	ν_exp	ν_calc	T
		k = 1			k = 2
1	333	533	−1.57
2	1004	1596	−1.45	54	59.48	−3.7
3	2015	3177	−1.46	288	293.89	−3.4
4	3385	5256	−1.45	914	864.93	−3.22
5	5081	7788	−1.46	2078	1959.3	−3.13
6	7069	10 686	−1.44	3990	3747.7	−3.08
7	9156	13 763	−1.38	6799	6301.6	−2.96
8	11 368	16 604	−1.20	10 460	9453.3	−2.75
9	12 825	18 371	−0.79	14 558	12 583	−2.36
10	12 894	37 630	−0.72	18 386	34 468	−1.61
11	10 736	41 212	−0.86	21 441	42 221	−1.95
12	39 033	45 466	−0.84	56 796	52 692	−2.17
13	44 078	49 330	−0.61	71 518	66 005	−2.41
14	49 924	51 045	0.08		83 884	−2.99
15	51 214	48 059	0.58		224 180	1.45
16		34 359	−32.8		73 345	−7.15
17		128 720	3.81		86 681	5.34
18		128 190	−1.23		110 930	−3.44

J	ν_exp	ν_calc	T	ν_exp	ν_calc	T
		k = 1			k = 2
1	333	533	−1.57
2	1004	1596	−1.45	54	59.48	−3.7
3	2015	3177	−1.46	288	293.89	−3.4
4	3385	5256	−1.45	914	864.93	−3.22
5	5081	7788	−1.46	2078	1959.3	−3.13
6	7069	10 686	−1.44	3990	3747.7	−3.08
7	9156	13 763	−1.38	6799	6301.6	−2.96
8	11 368	16 604	−1.20	10 460	9453.3	−2.75
9	12 825	18 371	−0.79	14 558	12 583	−2.36
10	12 894	37 630	−0.72	18 386	34 468	−1.61
11	10 736	41 212	−0.86	21 441	42 221	−1.95
12	39 033	45 466	−0.84	56 796	52 692	−2.17
13	44 078	49 330	−0.61	71 518	66 005	−2.41
14	49 924	51 045	0.08		83 884	−2.99
15	51 214	48 059	0.58		224 180	1.45
16		34 359	−32.8		73 345	−7.15
17		128 720	3.81		86 681	5.34
18		128 190	−1.23		110 930	−3.44

Table 5.

Open in new tab

Calculated and experimental (Ulenikov et al. 2002) k = 1 and k = 2, A₁ − A₂ splittings (in MHz) and their sensitivities in the ν₃ vibrational state of PH₃.

J	ν_exp	ν_calc	T	ν_exp	ν_calc	T
		k = 1			k = 2
1	333	533	−1.57
2	1004	1596	−1.45	54	59.48	−3.7
3	2015	3177	−1.46	288	293.89	−3.4
4	3385	5256	−1.45	914	864.93	−3.22
5	5081	7788	−1.46	2078	1959.3	−3.13
6	7069	10 686	−1.44	3990	3747.7	−3.08
7	9156	13 763	−1.38	6799	6301.6	−2.96
8	11 368	16 604	−1.20	10 460	9453.3	−2.75
9	12 825	18 371	−0.79	14 558	12 583	−2.36
10	12 894	37 630	−0.72	18 386	34 468	−1.61
11	10 736	41 212	−0.86	21 441	42 221	−1.95
12	39 033	45 466	−0.84	56 796	52 692	−2.17
13	44 078	49 330	−0.61	71 518	66 005	−2.41
14	49 924	51 045	0.08		83 884	−2.99
15	51 214	48 059	0.58		224 180	1.45
16		34 359	−32.8		73 345	−7.15
17		128 720	3.81		86 681	5.34
18		128 190	−1.23		110 930	−3.44

J	ν_exp	ν_calc	T	ν_exp	ν_calc	T
		k = 1			k = 2
1	333	533	−1.57
2	1004	1596	−1.45	54	59.48	−3.7
3	2015	3177	−1.46	288	293.89	−3.4
4	3385	5256	−1.45	914	864.93	−3.22
5	5081	7788	−1.46	2078	1959.3	−3.13
6	7069	10 686	−1.44	3990	3747.7	−3.08
7	9156	13 763	−1.38	6799	6301.6	−2.96
8	11 368	16 604	−1.20	10 460	9453.3	−2.75
9	12 825	18 371	−0.79	14 558	12 583	−2.36
10	12 894	37 630	−0.72	18 386	34 468	−1.61
11	10 736	41 212	−0.86	21 441	42 221	−1.95
12	39 033	45 466	−0.84	56 796	52 692	−2.17
13	44 078	49 330	−0.61	71 518	66 005	−2.41
14	49 924	51 045	0.08		83 884	−2.99
15	51 214	48 059	0.58		224 180	1.45
16		34 359	−32.8		73 345	−7.15
17		128 720	3.81		86 681	5.34
18		128 190	−1.23		110 930	−3.44