Abstract
Based on explicit definitions of biomolecular EPR spectroscopy and of the metallome, this tutorial review positions EPR in the field of metallomics as a unique method to study native, integrated systems of metallobiomolecular coordination complexes subject to external stimuli. The specific techniques of whole-system bioEPR spectroscopy are described and their historic, recent, and anticipated applications are discussed.
Graphical Abstract
EPR spectroscopy applied to systems of whole cells, extracts, or organelles can afford an integral, and at the same time detailed, picture of the sub-metallomes of paramagnetic transition ions.
© The Royal Society of Chemistry 2009
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